The 14th Annual

NC State University
Undergraduate Research Symposium

 

Engineering and Technology

Abstracts

 

Abstracts are listed in alphabetical order by the last name of the corresponding author.

 

 


 

Student Author(s): 

Trinity L. Biggerstaff

Department(s):

Materials Science and Engineering

Research Mentor(s)

Gerd Duscher/Materials Science and Engineering, Oak Ridge National Lab Condensed Matter and Science Division

Title of Presentation:

Atomic Characterization of Annealed Quantum Wells

 

 

Quantum well materials are used for a wide range of high efficiency optical devices including light emitting diodes and laser devices.  Here we study annealed and as-grown Nitrogen-doped GaAsSb quantum wells to determine the different optical properties of this infrared laser material.  We present results of high resolution scanning transmission electron microscopy (HRSTEM) with spherical aberration correction, used to determine thickness and interface roughness of these quantum well structures.  The transparency of Z-contrast imaging allows for the analysis of interface composition in high resolution images.  Additionally, microwave photoconductace decay is used to measure carrier lifetime. The thickness of the single quantum well in both the annealed and the as-grown specimen is measured to be 12.5 nm.  The interface closer to the surface in the annealed quantum well was determined to be an average of 0.9 nm thick while in the as-grown quantum well this interface was an average of 4.5 nm thick.  Similarly, the interface closer to the substrate in the annealed quantum well is an average of 0.78 nm and an average of 3.9 nm in the unannealed sample.  The interface roughness was also determined. Our study shows that annealing these structures sharpens both interfaces.



 

Student Author(s): 

Trinity L. Biggerstaff

Scott F. Abernathy
Myles L. Connor

Kristopher A. Darling

Department(s):

Materials Science and Engineering

Research Mentor(s)

Jon-Paul Maria/Materials Sciences and Engineering

William J. Borland/Dupont Microelectronics

Title of Presentation:

Big Effect of Etching on (BaSr)TiO3 Dielectric Materials

 

 

The selective etching is a critical step in the overall fabrication of high quality capacitor embedded printed wiring boards (PWB).  For the past year, Dupont has characterized the etching effects of CuCl2 + HCl, CuCl2 + NH3OH, and Black Oxide, which is sulfuric acid with hydrogen peroxide on thick film capacitor composed of Cu electrodes with BaTiO3 + glass filler for the dielectric material.  These capacitors were unable to withstand the etching process.  The problem to be addressed is to see if our thin film capacitors composed of Cu electrodes with (BaSr)TiO3 as the dielectric material will outlast Dupont’s etching procedures while resulting in minimal degradation of the dielectric.  The (BaSr)TiO3 based capacitors were subjected to the same three etchants as described by Dupont.  Electrical measurements such as capacitance, loss tangent and leakage current were conducted versus exposure time to the specified etchants.  SEM was used to characterize surface morphology after etching.  From the results it was concluded that CuCl2 + HCl, CuCl2 + NH3OH, and Black Oxide have little effect or rather the degradation of dielectric properties of (BaSr)TiO3 are independent of etching time.



 

 

 

Student Author(s): 

Robert D. Boaz

E. Lindsay Harrell

Matthew P. Jones

John M. Long

Department(s):

Biological and Agricultural Engineering

Research Mentor(s)

Larry F. Stikeleather/Biological and Agricultural Engineering

Ratna Sharma/Biological and Agricultural Engineering

Title of Presentation:

Semi-Automated Conversion of Waste Vegetable Oil to Biodiesel

 

 

Biodiesel is becoming a popular alternative fuel due to environmental concerns and rising oil prices.  Current conversion processes require much time and human input.  A semi-automated Biodiesel conversion system will allow hobbyist users to produce this fuel with lower costs and little experience.  The conversion process involves a single stage transesterification process.  The physical inputs are waste vegetable oil, methanol and potassium hydroxide.   The outputs are glycerine and biodiesel.  The system is composed of seven containers and two pumps connected by tubing and controlled by five solenoid valves.  The system is powered by 120VAC. A laptop with Labview software is used to control the system through a data acquisition card and solid state relays mounted on a printed circuit board.   The relays, transformers, and electrical connections are contained inside a control box.  The system is designed for minimum exposure to the chemicals used during the conversion process.  Labview adds the desired amount of potassium hydroxide needed for the conversion based on user input at the beginning of the process.  The process starts once five liters of waste vegetable oil has accumulated in the storage tank. In tests the system has successfully produced four liters of biodiesel per run.

 



 

 

Student Author(s): 

Sarah J. Bolls

Rachel L. Doss

Adam C. Pearce

Department(s):

Materials Science and Engineering

Research Mentor(s)

Ron O. Scattergood/Materials Science and Engineering

Keith Dawes/Materials Science and Engineering

Mike Antony/Allvac Ltd.

Title of Presentation:

Improving the Mechanical Properties of Semi-Austenitic Stainless Steels

 

 

Semi-Austenitic stainless steels used in the die cast industry need mechanical properties such as ductility, high hardness and good thermal fatigue resistance. The objective of this project is to improve the mechanical properties of a material whose composition was determined using Thermo-calc software.  This project employs the use of multiple solutions to suggest and test approaches to improve the mechanical properties of the material based on the microstructure findings.  The microstructure and volume percentage of the existing phases is determined using two approaches, optical microscopy and X-Ray diffraction methods.  Crack propagation in the tensile and thermal fatigue samples is characterized using SEM microscopy and the low ductility in the tensile samples is analyzed for explanation. Suggestions for improvement include variations in chemistry and wrought processing.  Research and Development forging trials are run to confirm the accuracy of the recommended processing adjustments.  The data is compared to the original data to determine improvements in ductility and hardness.  The optical and mechanical test results provide methods to determine the effectiveness of the heat treatment on mechanical property improvement and offer suggestions for further improvements and testing procedures for future research in semi-austenitic stainless steels.



 

 

 

Student Author(s): 

Stephanie E. Brandon

Julie R. Gentry

Department(s):

Biomedical Engineering

Textile Engineering

Research Mentor(s)

Marian G. McCord/Biomedical Engineering

Title of Presentation:

Characterizing the Behavior of the Thermoresponsive Polymer N-Isopropylacrylamide (NIPAAm) as a Tissue Engineering Substrate

 

 

Poly(N-isopropylacrylamide), more commonly referred to as Poly-NIPAAM, is a thermoresponsive polymer that reversibly changes from a hydrophilic solution to a hydrophobic gel with change in environment temperature. This property makes this polymer an ideal substrate for tissue engineering, especially when used as a non-invasive method of cell culture and harvest. This experiment evaluates the surface characteristics and cellular response of  Poly-NIPAAM as a tissue culture substrate.  NIPAAM monomer was grafted to polystyrene culture dishes using a novel method of treating a monomer solution with atmospheric plasma to graft the monomer to the dishes.  The grafted surface was analyzed for thermal response using atomic force microscopy.  Images were taken using tapping mode; in air, vacuum, and liquid conditions, over a range of temperatures.  Surface conditions in fluid over 25-40οC mimic the environment in which the cells interact with the surface during cell attachment and release.  Morphological and hardness changes in the surface were characterized.  Cellular response to the surface was characterized by culturing human hepatocytes on the NIPAAM substrate to confluency.  The cells are harvested in confluent sheets  by dropping the temperature of the culture dish below the polymer’s transition temperature, 32οC; peeling off the cell sheets, and reculturing them in a new dish.  The adhesion and proliferation of the cells before and after harvesting

is reported.



 

 

 

Student Author(s): 

Necia B. Chavis

David Brandner

Nina Chavis

Mary Ellington

Jacob Thompson

Alison Watkins

Department(s):

Chemical and Biomolecular Engineering

Food Science

Research Mentor(s)

Christopher Daubert/Food Science

Steven Peretti/Chemical and Biomolecular Engineering

Brian Farkas/Food Science

Title of Presentation:

Carbohydrate Replacement Using a Soy Protein Derivative

 

 

The goal of this project is to evaluate a new value-added processing scenario for soybeans that modifies soybean meal, a low value byproduct of soybean processing that contains nearly 50% protein, into a food ingredient that functions similarly to a pre-gelatinized starch. The proposed modified soy protein isolate, MSPI, would function as a thickening agent in food processing applications.  The design efforts focused on two objectives: 1) analysis of the functional characteristics of the MSPI; and 2) the design and economic analysis of a scaled-up process.  Analysis of the MSPI consisted of testing water holding capacity and viscosity as a function of shear rate.  A pre-gelatinized starch and an unmodified soy protein isolate were also tested for comparison.  The pre-gelatinized starch was used for functional comparison while the unmodified soy protein isolate was used to determine the effectiveness of the modification.  Results showed that a 10 wt% MSPI had characteristics similar to a 3 wt% pre-gelatinized starch.  Solutions prepared from each ingredient  behaved like non-Newtonian fluids, with MSPI  being the most viscous.  Each solution also exhibited water holding capabilities, with MSPI having the highest.  Process design optimization, cost assessments, and product value analysis are being evaluated to determine the economic viability of producing MSPI on a larger scale.  From this, a recommendation will be made to the North Carolina Soybean Grower's Association for large scale development of this process.



 

 

 

Student Author(s): 

Mark Y. Chen

Department(s):

Food Science

Biological and Agricultural Engineering

Research Mentor(s)

Kevin M. Keener/Food Science

Title of Presentation:

Finding Dielectric Constant and Loss Factor of Egg Components at Different Frequencies and Temperatures

 

 

Approximately 5.5 billion dozen shell eggs were produced in the United States in 2003.  There is a concern regarding safety of shell eggs.  CDC reports that approximately 1.3 million illnesses occur every year from Salmonella enteritidis in shell eggs.  This potentially fatal disease can be removed by pasteurizing shell eggs.  Currently, a hot water system is used to pasteurize (heat but not cook) some shell eggs.  However, this system is inefficient and costly to operate.  Microwave heating is a possible alternative process.  Microwave processes have been successfully developed to heat pasteurize other foods.  Microwave processing requires knowledge of dielectric properties: dielectric constant (commonly denoted as e’) and dielectric loss factor (e’’).  There is little dielectric data available for eggs.  Thus, a study was undertaken to collect dielectric properties information on shell egg components.  In this study, two ages of eggs were tested: fresh and aged.  The eggs were separated out by components: thick and thin albumen, yolk, mixed albumen, and shell.  The dielectric constant and loss factor were measured for each component over a temperature range of 0°C-70°C and a frequency span of 300 mHz – 3000 mHz.  The fresh and aged eggs demonstrated a general decline in e’ and e’’ as frequency increased.  The average value of e’ of fresh eggs at 300 mHz, 0°C for the thick albumen was 39.13.  The average at 3000 mHz at the same temperature was 36.16.  Similarly, the average e’ of fresh eggs at 300 mHz, 0°C for the yolk was 51.57.  The average at 3000 mHz at the same temperature measured 44.65.  The collection of these data will provide necessary information to develop an efficient microwave heating process for shell eggs.

 



 

 

 

Student Author(s): 

Brandon R. Clark

Department(s):

Nuclear Engineering

Research Mentor(s)

Mohamed A. Bourham/Nuclear Engineering

Title of Presentation:

Theoretical Thermal Analysis of ITER Divertor

 

 

Magnetically confined fusion reactors are seen by many to be the answer to the World’s energy needs.  However, before they can be implemented into the commercial power industry many engineering factors must be considered.  The International Thermonuclear Experimental Reactor (ITER) has been designed to test MCF technology and prove the capability of future MCF reactors as a safe, efficient, and profitable source of electricity.  This research is focused on the divertor of ITER, which is a major component of any magnetic confinement fusion reactor. The divertor exhausts the flow of energy from charged particles produced in the fusion reactions and removes helium and other impurities resulting from the reactions, and from interaction of plasma particles with the material walls.  The very nature of the divertor implies that it is subjected to very high heat fluxes during abnormal events and hard disruptions.  Using ITER design parameters a theoretical thermal analysis  is performed to test various elements/compounds to conclude if they are acceptable divertor materials.  The main focus is on analyzing the materials under transient operation, that is, when ITER experiences a disruption in operation, resulting in a high heat load being dumped on the divertor.  The conduction equation is employed with various manipulations allowing for an accurate model of the divertor during both normal and transient operation.



 

 

Student Author(s): 

Matthew H. Clayton

Department(s):

Civil Engineering

Research Mentor(s)

Gnanamanikam Mahinthakumar/Civil Engineering

Title of Presentation:

Groundwater Contamination Source Identification Using Hybrid Optimization Methods

 

 

Locating the source of groundwater contamination is an important part of cleaning up groundwater pollution. One way to locate the source is to solve an inverse problem that uses downstream well data to estimate the source. Currently, using a hybrid of global and local search methods we are able to estimate the location of a contaminant source in a simplified two-dimensional setup, but this is not useful when there are possibly multiple sources in the same area. In this paper, we modify and expand existing single-source groundwater contamination inverse solvers to tackle the more difficult scenarios of multiple source identification. In order to handle more than one source we modify the groundwater transport model, expand the optimization methods, and create different visualizations of the problem to better understand the solution. We also compare different optimization methods to find which are best for a multi-source problem, examine the difference between the objective function error versus the actual solution error, and explore the possibilities of a non-unique solution to the problem. The long-term goal of this research is to expand this approach to more realistic three-dimensional problems in collaboration with the North Carolina Department of Environmental and Natural Resources.



 

 

 

Student Author(s): 

Myles L. Connor

Department(s):

Materials Science and Engineering

Research Mentor(s)

Jerry Cuomo/Materials Science and Engineering

Title of Presentation:

Pure and Renewable Hydrogen Production

 

 

With the onset of increasing fossil fuel limitations and environmental awareness, the search for alternative energy sources has increased. Recent strides in hydrogen fuel cell technology and the utilization of these devices in conjunction with Hydrogen gas production has brought a new light to the energy conversion community. In order to implement a feasible hydrogen fuel cell system to combat energy efficiency, a reliable and renewable source of pure hydrogen gas must be found. The production of pure hydrogen from the chemical reaction between pure aluminum (Al), pure gallium (Ga) and water (H2O) is such a source. Aluminum readily reacts with oxygen to form aluminum oxide (Al2O3), when gallium is applied to pure aluminum it hinders the passivating Al2O3 film making it possible for the aluminum to react with the oxygen in H2O leaving pure H2 gas. The resulting product is Al2O3 plus Ga. The Ga can be separated and the Al2O3 reformed back to pure Al, thus eliminating the production cycle of raw Al. This process is a clean and completely renewable source of hydrogen gas needed to power fuel cell systems.

 



 

 

Student Author(s): 

Johanna L. Cornelius

Brian D. Hehr

Andy O. Li

Stephen B. Yodersmith

Department(s):

Nuclear Engineering

Research Mentor(s)

Mohamed A. Bourham/Nuclear Engineering

Ayman I. Hawari/Nuclear Engineering

Man-Sung Yim/Nuclear Engineering

Title of Presentation:

Mobile Radiation Detection System for First Responders

 

 

Our nation must be well prepared to respond to and mitigate the effects of possible acts of radiological terrorism. Law enforcement and emergency responders must be trained and well equipped to locate a radiation hazard and deal with it appropriately. This project proposes a multi-tiered system for efficient, mobile detection and response to radiological terrorism.

            At the local level, active personal dosimeters could be distributed to first responders—police officers, firefighters, and emergency medical technicians—and used for initial detection of radiation threats. Dosimeters equipped with a radiofrequency link can detect the dose to first responders and broadcast to a central monitoring system. To ascertain more information about the nature of the threat, response would proceed to higher tiers, which utilize more sophisticated detection equipment. The Mobile Accurate Radiological Assay and Tracking Hunter of Nuclides (MARATHON) device is proposed. The MARATHON system uses room temperature detectors to provide localization and nuclide identification from a safe distance.

            Likely sources of material for a radiological dispersal device include the gamma and neutron emitters: Co-60, Cs-137, Ir-192, and Cf-252. Conventional methods used for dual neutron-gamma detection involve separate detectors for each radiation type. The design of the MARATHON device, however, employs a single detector for both neutron and gamma detection, to reduce size and weight thereby enhancing mobility. Many detector types, including High Purity Germanium (HPGe), Cadmium-Zinc-Telluride (CZT), and scintillation detectors were examined. Detector response to a mixed neutron-gamma source was assessed using SYNTH spectroscopy program, Monte Carlo N-Particle Transport Code, and theoretical models. Of the detectors studied, the Lithium-Iodide Scintillator was determined to best meet the needed criteria and performance capabilities.

            The MARATHON device performs source localization via triangulation, using a three-detector system. Source-to-detector distance is determined using a triangulation algorithm based on the rotational angle of each detector. Analog/digital solver provides distance to source measured from the central detector. Preliminary simulations have shown that the MARATHON system could enhance the ability of emergency response teams to respond to acts of radiological terrorism.


 


 

Student Author(s): 

Harsh S. Desai

Department(s):

Nuclear Engineering

Research Mentor(s)

Mohamed A. Bourham/Nuclear Engineering

Title of Presentation:

Cerenkov Radiation

 

 

The purpose of this project is to analyze the effect of change in the NCSU PULSTAR reactor power on the produced Cerenkov radiation. Cerenkov radiation results when a charged particle, most commonly an electron, exceeds the speed of light in a dielectric medium through which it passes. Moreover, the velocity of light that must be exceeded is the phase velocity rather than the group velocity. The phase velocity can be altered dramatically by employing a periodic medium, and in that case one can even achieve Cerenkov radiation with no minimum particle velocity — a phenomenon known as the Smith-Purcell effect. In a more complex periodic medium, such as a photonic crystal, one can also obtain a variety of other anomalous Cerenkov effects, such as radiation in a backwards direction (whereas ordinary Cerenkov radiation forms an acute angle with the particle velocity).

            The overall intensity of Cerenkov radiation is proportional to the velocity of the inciting charged particle and to the number of such particles. Unlike fluorescence or emission spectra that have characteristic spectral peaks, Cerenkov radiation is continuous. The objective of this project is to design, build, and test a light sensitive monitor that measures the intensity of Cerenkov radiation in the NCSU open pool PULSTAR reactor. Cerenkov radiation intensity is proportional to the reactor power, therefore measuring the intensity of the radiation would give a measure of reactor power. Measured Cerenkov intensity versus reactor power was obtained and data have been used to derive a general equation that relates reactor power to measured Cerenkov intensity for the specifically selected light sensitive elements.

            Six CdS photo resistors were used to measure the intensity of Cerenkov radiation at reactor power levels of 0, 100, 300, 500, and 700kW. Obtained data were fit to a power law with 0.997 regression accuracy. When using the constructed device to measure reactor power, the measurements were accurate with an average error of 2.55%.


 


 

Student Author(s): 

Brandy Dixon

Leslie O'Loughlin

Carole Mertes

Department(s):

Materials Science and Engineering

Research Mentor(s)

Keith Dawes/Materials Science and Engineering

Title of Presentation:

Alternative Supports for Propane Tanks

 

 

The propane industry has always used cement blocks as supports for propane tanks in residential, commercial, and military applications.  American Welding and Tank and National Gas Distributors are searching for a lightweight alternative to these concrete blocks.  For a replacement to be feasible, it must meet the following criteria: fire-retardant, comparative cost to concrete blocks, and compressive strength capabilities to support weights in excess of 5000lbs for extended time periods.  Two possible solutions include concrete blocks made of lightweight aggregate and polypropylene blocks.  Using lightweight concrete aggregate, reductions in weight of up to 30% can be obtained with only slight decreases in strength.  While regular concrete consists of typical gravel and sand, the lightweight aggregate chosen consists of small slate rocks and ground slate.  For testing purposes, three batches of concrete cylinders, one made of lightweight rock and lightweight sand, one of lightweight rock and regular sand, and one of regular gravel and regular sand, were constructed.  One cylinder of each batch was then compression tested at seven, 14, and 21 days after mixing.  The other possible concrete alternative selected was a polypropylene block. New block designs were constructed using the SolidWorks software, and then tested using CosmosWorks to determine their capability to support propane tanks.

 


 

 

Student Author(s): 

Brent Duffy

Department(s):

Mechanical and Aerospace Engineering

Research Mentor(s)

Andre Mazzoleni/Aerospace Engineering

Title of Presentation:

Dynamics of Solar Sail Space Propulsion with Mission Applications

 

 

Solar sailing is an innovative form of space propulsion that relies on solar light radiation as its source of energy. This study analyzes the general dynamics of solar sail propulsion with applications to interplanetary rendezvous missions and Lagrange orbiting. Models are developed to demonstrate the performance characteristics of solar  sailing for various interplanetary rendezvous missions using spiral  trajectories. This includes all of the outer planets as well as the inner planets. Optimal conditions are determined based on the sail pitch angle and sail lightness number. In comparison to minimal-energy Hohmann transfers, solar sails are shown to have shorter trip times at sufficient sail lightness numbers. Models are also developed demonstrating a method for extending the five natural Lagrange points of a restricted three body system into a continuum of stationary solutions that are dependent only on the sail lightness number and sail attitude. The new stationary positions would  be beneficial for many space applications, such as relieving the overcrowded equatorial geostationary orbit plane, establishing an early solar storm warning station, and reaching high inclination orbits.

 



 

 


 

Student Author(s): 

Jason R. Elkins

Department(s):

Nuclear Engineering

Research Mentor(s)

Mohamed Bourham/Nuclear Engineering

Ayman Hawari/Nuclear Engineering

Ron Beliner/Nuclear Engineering

Title of Presentation:

Characterization of a Neutron Beam

 

 

Before routine use, the neutron beam at the newly installed Neutron Imaging Facility (NIF) at North Carolina State University’s PULSTAR Reactor needs to be fully characterized.  The characterization process involves the use of a collimated beam of thermal neutrons at the 5 meter image plane.  The characterization of the neutron beam includes finding the thermal neutron flux distribution by gold foil activation techniques as per ASTM Standard E262-97.  A cadmium ratio for the imaging facility will be measured.  The beam size, spread and uniformity will be determined.  Also, the beam quality will be determined using ASTM Standard E545-99.  Finally, the beam resolution or L/D ratio can be found using the ASTM Standard E803-91.

 

 



 

Student Author(s): 

Allison R. Finger

Department(s):

Biomedical Engineering

Research Mentor(s)

Elizabeth G. Loboa/Biomedical Engineering

Title of Presentation:

Chondrogenic Differentiation of Human Mesenchymal Stem Cells in 3D Cultures: Ramp and Steady Applications of Cyclic Hydrostatic Pressure

 

 

The ability to engineer structurally robust cartilage tissue that can interact positively with a host could provide less invasive alternatives to current treatments for cartilage damage (e.g., total joint replacements). Hydrostatic pressure can help maintain the extracellular matrix of cartilage tissue and it can also facilitate chondrogenesis in mesenchymal stem cells (MSCs). Human MSCs from two donors seeded in 2% agarose constructs were loaded under cyclic hydrostatic pressure for 4 hours per day at 1 Hz for 14 days. Constructs were loaded in a 1L pressure vessel connected to a hydraulic cylinder powered by an MTS 858 Mini Bionix II load frame. The first set of constructs were cyclically loaded using a ramping technique such that the first day the constructs were loaded at 1 MPa, followed by an increase in pressure each day by 0.5 MPa so that the constructs were loaded at 7.5 MPa on day 14. A second set of constructs were cyclically loaded at 7.5 MPa for all 14 days, and a control set of constructs were not loaded, but were placed in an oil-filled container for 4 hours per day to mimic the in vitro environment of the loaded constructs during pressure application. Real time RT-PCR analysis was performed at days 0, 4, 9, and 14 to determine the change in expression of Sox9, aggrecan, and collagen I and II.

 


 

 


 

 


 

Student Author(s): 

Darryl Glanton

Eric Austin

Brett Godin

Ginger Wheeler

Department(s):

Materials Science and Engineering

Research Mentor(s)

Mike Rigsbee/Materials Science and Engineering

Title of Presentation:

Non-isothermal Aging of 7085 Aluminum Alloy

 

Alcoa’s 7085 aluminum alloy combines high strength with adequate corrosion resistance when overaged.  7085-T7X aluminum is currently used in aerospace applications for the Airbus A380.  However, Alcoa wishes to use this alloy for mold blocks, which will require a much more economical heat treatment process.  The current aging process calls for two isothermal steps – three hours at 260°F and 17 hours at 315°F.  Data suggests that a unique model based on continuous heating will produce comparable strength and corrosion resistance at considerably shorter aging times.

 

 

 



 

 

 

Student Author(s): 

Jessica M. Gluck

Department(s):

Textile and Apparel, Technology, and Management

Research Mentor(s)

Martin W. King/Textile and Apparel, Technology, and Management

Gerardo Montero/Textile and Apparel, Technology, and Management

Title of Presentation:

Electrospun Polycaprolactone Nanofiber Scaffolds for Tissue Engineering

 

 

Polycaprolactone (PCL), a bioresorbable polymer, was electrospun into nanofibers in the form of nonwoven scaffold structures for tissue engineering.  The objective of the study was to determine the optimal spinning conditions for preparing scaffolds for the culture of hepatocytes.  Such tissue engineered structures will be valuable in the repair and replacement of diseased liver tissue. In order to find the optimal spinning conditions for PCL, several different solvents and solutions were examined during electrospinning trials that were run with different capillary diameters, flow rates and voltage potentials.  Finally a 3:1 chloroform : methanol mixture was found to be the optimal solvent.  The scaffolds were prepared in different thicknesses by varying the duration of the electrospinning process under whipping conditions. Scanning electron microscopy was used to determine the fiber morphology, nanofiber diameter and pore size distribution. The electrospun scaffolds were sent to UNC-CH Medical School for in vitro hepatocyte culture.



 

 


 

Student Author(s): 

Jeremy M. Gobien

Department(s):

Materials Science and Engineering

Research Mentor(s)

Zlatko Sitar/Materials Science and Engineering

Title of Presentation:

Silicon-On-Diamond, an Engineered Substrate for Advanced

Thermal Management of Silicon Devices

 

Silicon-On-Diamond (SOD) is envisioned as an advanced engineered substrate aimed at improving thermal management of silicon-based electronic devices and integrated circuits.  This paper incorporates finite element analysis using ANSYS™ to study the relative thermal management capability of SOD with respect to Silicon-On-Insulator (SOI) and bulk silicon. The modeled SOD structure comprised a 1.5 µm thick Si layer on a 100 µm thick diamond substrate. Results of the analysis showed SOD can dissipate 24 times greater heat input than SOI for a surface temperature of 85°C. When compared to bulk silicon it was found that SOD can dissipate 5 times as much heat input for the same surface temperature increase.  These results clearly show the large potential gains in thermal management capability for SOD substrates in comparison to SOI and bulk silicon. Significant further improvements in the heat management capability of SOD are expected with thinner Si device layers.



 

 

 

Student Author(s): 

Dara V. Gough

Leslie H. Jimison

William P. Davis

Brendon S. Bass

Department(s):                   

Materials Science and Engineering

Research Mentor(s)

Jerry Cuomo/Materials Science and Engineering

Keith Dawes/Materials Science and Engineering

Title of Presentation:

A Study of the Adhesion of an Anti-Corrosion Coating on a Steel Surface

 

 

Northrop Grumman approached our senior design team with a challenge concerning the adhesion of their current anti-corrosion coating, Type 4 Military Paint, on a steel substrate.  To attack the problem, a study of the affect of adhesion of the paint was performed as a function of surface preparation.  Prior to experimentation, the steel substrate was uniformly degreased using a series of appropriate solvents. The surface of the steel substrate was then plastically deformed via grit blasting in order to achieve a variety of surface profiles between samples. Blasting pressure and the type of grit were altered in order to create various peak to trough distances and to modify the angularity of the surface peaks, respectively.  The two part Type IV military coating was then applied to both clean and contaminated steel surfaces.  A pull test was performed in order to determine the dependence of adhesion on both the surface profile and contamination of the steel surface. From the pull test, it was determined that a clean surface with each profile tested exceeded the minimum specifications presented by Northrop Grumman.  The contaminated surfaces, however, demonstrated a very weak level of adhesion, which was below the aforementioned specifications.   From these results we were able to offer Northrop Grumman a quantitative analysis of paint adhesion with respect to surface profile.

 

 



 

 


 

Student Author(s): 

Kristen D. Hambridge

Amanda F. Irons

Susan M. Oliver

Cheryl A. Speight

Melissa A. Lee

Department(s):

Biomedical Engineering

Research Mentor(s)

Simon Roe/College of Veterinary Medicine

Duncan Lascelles/College of Veterinary Medicine

Title of Presentation:

A System to Standardize the Velocity of a Canine Patient During Gait Analysis

 

 

The purpose of the ‘Canine Velocity Standardization System’ is to decrease the number of useless trials by controlling a canine handler’s velocity, thereby controlling the canine’s velocity.  The velocity of the canine needs to be calculated instantaneously so that useless trials can be eliminated and five trials, during which the canine’s velocity falls within 1.7 to 2.1 m/s, can be obtained.  The system is comprised of an audio device for the handler, Photogate sensors and a computer software package to determine velocity, and a fence-like barrier to corral the dog along the force pad.  The fence is constructed from aluminum, PVC piping, and machined plexi-glass fittings for the Photogate sensors.  The canine is led along the force pad at approximately the same rate as the handler, whose steps are guided by a continual beeping of a metronome.  The force readings which are generated by the paws of the canine are processed into a movie within a computer program.  The LabPro software, coupled with the software generating force data, creates  velocity and acceleration data as the canine’s chest breaks the laser beam crossing from the lasers to the sensors at three points along the length of the force pad.  These two readings allow for more efficient collection and assessment of canine lameness.

 



 

 


 

Student Author(s): 

Bennett S. Hawley, Jr.

Department(s):

Forestry and Environmental Resources

Research Mentor(s)

Stacy A. C. Nelson/Center for Earth Observation; Forestry and Environmental Resources

Title of Presentation:

Satellite Assessment of Urban Land-use Development Using Multi-date Landsat TM

 

 

Many U.S. cities are experiencing rapid levels of population growth.  This growth places demands on our natural resources through, land use conversions of natural systems, clearing of old-growth forest stands, conversions of wetland areas, and impacts to clean air and water.  As urban land use continues to intensify within areas such as Raleigh, North Carolina, planning efforts to manage environmental resources are often focused on current developmental trends, rather than future trends affected by escalated growth.  This is, in part, due to the lack of accurate land use change data as the trend in rapidly intensifying urban areas is to not only expand outward from the perimeter, but to also to increase higher density development from the perimeter inwards (infilling).  This of type of high-density growth can be very difficult to assess in terms of spatial change, as changes may occur rapidly and without the normal signs of rural landscape development.  Remote sensing may provide the means to assess changes occurring within highly developed urban areas, especially where this land use change is suspected of occurring both outside of the metropolitan boundaries as well as inside.  In this study, I investigate the use of multi-date Landsat TM data to quantify three levels of urban development within the Raleigh, North Carolina metropolitan area over the past twenty years.  Quantifying these changes in urban land is necessary to fully understand the effect of high-density development versus classic urban “sprawl” into rural areas and the potential for each to impact natural resources.

 



 

Student Author(s): 

Adam Hoffman

Department(s):

Wood and Paper Science

Research Mentor(s)

Hasan Jameel/Wood and Paper Science

Title of Presentation:

Conversion of Office Waste to Fermentable Glucose

 

 

There is a strong interest in the development of alternative fuels to replace depleting supplies of petroleum.  Ethanol produced from biomass is seen as a promising alternative.  Mixed office waste is an inexpensive source of cellulose material that is in abundant supply and is difficult to recycle back into paper.  In this study, the feasibility of converting the cellulosic portion of mixed office waste to fermentable glucose was evaluated.  Enzymatic hydrolysis with Trichoderma reesei cellulase was performed on a hardwood market pulp, blank standard copy paper, standard copy paper with deskjet printing, and standard copy paper with laser jet printing to evaluate the impact of ink and paper fillers on the conversions that can be achieved.  It was observed that the toner based inks did not impact the hydrolysis process but the dispersible inkjet inks did.  These findings will help determine the ultimate potential of using mixed office waste for glucose production.



 

 

Student Author(s): 

Anne M. Hooper

Laura E. Patterson

Jessica E. Sutton

Michael J. Schott

Department(s):

Biological and Agricultural Engineering

Research Mentor(s)

William F. Hunt/Biological and Agricultural Engineering

Garry L. Grabow/Biological and Agricultural Engineering

Title of Presentation:

Rainwater Catchment Systems & Analysis

 

 

Water is a precious natural resource necessary for life. Systems and other conservation procedures are being developed in North Carolina in order to preserve its use and availability. Rainwater catchment systems being used in residential and commercial areas have become a growing interest. Therefore our design team was tasked to create a computer model in Microsoft Excel with the capabilities to size rainwater catchment systems throughout the state of North Carolina.  The model is based on site water supply and demand; and has been used to size rainwater catchment systems located in Craven and Lenoir Counties. Data from these selected sites was used to establish statewide creditability for the model in future uses. A website and user’s manual were also developed to accompany the model and enhance the understanding of rainwater catchment systems.

 



 

Student Author(s): 

Samia Ilias

Department(s):

Chemical and Biomolecular Engineering

Research Mentor(s)

Saad A. Khan/Chemical and Biomolecular Engineering

Title of Presentation:

Novel Composite Polymer Electrolytes Based on Poly(ethylene oxide) Blends and Silica Nanoparticles

 

 

Polar polymer systems such as poly(ethylene oxide) (PEO) and oligo-poly(ethylene glycols) are of great interest because they allow for the solvation of ions such as lithium. This property lends itself to many applications, specifically novel lithium batteries for automobiles and portable electronic devices among others. Ideal electrolytes for batteries have high conductivity, mechanical stability, and are easily processable. The design of an ideal electrolyte, therefore, requires the optimization of mutually exclusive properties. Our objective in this work is to evaluate the mechanical properties of PEO/PEGdm(250) blends composite electrolytes through rheology. The effects of blend ratio as well as silica nanoparticles (FS) surface chemistry will be studied.  Two different types of FS particles were employed: A200, which has –OH groups on the surface, and R805, which has 50% of the –OH groups replaced with octyl chains. The PEO used in these experiments contains inorganic fillers; therefore a purification step prior to blending was required in order to remove them.  Thermogravimetrical analysis confirmed the efficiency of our purification protocol as the purified samples showed 100% weight loss.  Dynamic rheological experiments revealed that blends of PEO/PEGdm(250) and FS containing up to 20 wt% of the low-MW component exhibit a gel-like behavior within the frequency range studied, i.e. the elastic modulus G' is higher than the viscous modulus G'; for all frequencies.  As the concentration of the low-MW component increases, G'; starts to dominate at lower frequencies indicating that the material transitions from gel to liquid.  Though a decrease on the moduli is observed with the addition of PEGdm(250), this is not noticeable when 10 wt% of the low-MW component is added to the blends.  This result is very appealing since the presence of a liquid component in the system can increase the ionic conductivity of electrolytes while the mechanical properties remain unaltered.


 


 

Student Author(s): 

Jennifer D. Jassawalla

Nicholas J. Jardine

Jillian G. Rouse

Christopher W. Simms

Jennie R. Stancil

Department(s):

Biomedical Engineering

Research Mentor(s)

Michael D. Boyette/Biological Engineering

Elizabeth G. Loboa/Biomedical Engineering

Frank C. Abrams/Biomedical Engineering,

Brooke N. Steele/Biomedical Engineering

Peter L. Mente/Biomedical Engineering

Glenn M. Walker/Biomedical Engineering

Ola L. A. Harrysson/Industrial Engineering

Title of Presentation:

Bioreactor for Applying Fluid Shear Stress to Mesenchymal Stem Cells in 2D and 3D Cultures

 

 

Mesenchymal stem cells (MSCs) have been isolated from bone marrow, trabecular bone and adipose tissue and have the ability to differentiate into a variety of skeletal tissues.  Dr. Loboa’s research group in the Cell Mechanics Laboratory (http://www.bme.ncsu.edu/labs/cml) at NCSU investigates the combination of chemical and mechanical factors that influence and regulate differentiation of human MSCs (hMSCs). To promote osteogenic differentiation of hMSCs, there is a need in the CML for a device that can apply a range of fluid shear stresses to hMSCs in two-dimensional (2D) and three-dimensional (3D) cultures while maintaining suitable conditions for cell viability and differentiation (37°C, 5% CO2, mass transport).  Dr. Loboa’s group would also like to use the bioreactor to perfuse cells through 3D scaffolds to allow for cell-scaffold adhesion and cell proliferation at low flow rates/shear stresses.

            Six 2D and 3D chambers were designed and fabricated for the bioreactor. Interchangeability of the chambers allows for the choice of applying fluid shear stress to 2D or 3D cell cultures.  Furthermore, 3D chambers have been designed to accommodate several scaffold sizes ranging from ¼’’ to 1’’.  The peristaltic pump consists of six flow channels and supplies synchronous flow to each of the six chambers. Since the peristaltic pump only applies pulsatile flow, up to six dampeners may be connected to the flow channels to produce steady flow as needed.  Flow rates can be varied from 0.4 ml/min to 28 ml/min on the pump to provide the appropriate shear stresses.  Gas permeable silicon tubing with an inner diameter of ¼’’ is used for oxygen exchange between the system and surrounding environment.  A media reservoir is available to ensure enough media is able to fill the entire system. Placing the chambers and reservoir in an incubator with an oxygen tension regulator controls the desired CO2 and O2 conditions. 



 

 


 

Student Author(s): 

Brian Johnson

Jason Krahnke

Josh Nowak

Justin Arrington

Robert Fairlie

Department(s):

Nuclear Engineering

Research Mentor(s)

Paul J. Turinsky/Nuclear Engineering

Michael J. Doster/Nuclear Engineering

Korukonda Linga Murty/Nuclear Engineering

Title of Presentation:

The Southeast Universities Nuclear Reactors Institute for Science and Education (SUNRISE) Reactor Core Design

 

 

The goal of the SUNRISE project is to design a reactor for use in experimental research specifically geared to Generation IV reactor development.  Generation IV reactors are being developed by the US Department of Energy for deployment 20-30 years from now, hence represent a dramatic change from designs that more effectively address nuclear safety, economics, proliferation resistance, and nuclear waste burden.  The research reactor would allow test fuel assemblies to be inserted into the reactor, where they would be exposed to representative neutron fluxes, invoking conditions that could result in fuel cladding failure.  SUNRISE has two major design constraints, a limit of 20 MW thermal including test cell and a 20 w/o enrichment limit on the fuel. 

            The U.S. DOE Nuclear Energy Research Advisory Committee Generation IV Technology Roadmap provided information on proposed Gen IV concepts, designs, and technological gaps.  Of special interest was the type of fuels, moderator (if utilized) and coolants being considered, since these would be the main focus of the testing done in the SUNRISE reactor.  Flux, temperature, and pressure conditions would also affect the overall design of the reactor and test capsule.

            As it stands, only the research requirements for the Gen IV reactors are considered; very little information has been found regarding existing research reactors.  What has been found is that the reactor must be capable of the following:

 

1.         Accommodate fast and thermal neutron spectrums.

2.         Testing multiple fuels, coolant and cladding options.

3.         Temperatures ranging up to 1000 ºC

4.         Neutron fluxes up to 5x1014 n/cm2s and wide range of power densities.

5.         Safely supporting cladding failure research.


The project requires computer modeling of neutron flux and temperature distributions in the test cell and driver region.  HELIOS codes have been employed using reflective boundary conditions for both a thermal and fast test cells in order to determine the target neutron energy spectra desired.  These codes have also been employed to model the SUNRISE core, which consists of driver, buffer (energy spectra shifter) and test cell regions in addition to radial reflector. There is also a working code for modeling the heat flux and temperature distributions in the driver and buffer regions.  Currently the project team is defining the reactor geometry and composition within our design constraints to meet the design objective for both neutronic requirements as well as thermo-hydraulic requirements.

 


 


 

Student Author(s): 

Mary Ellen M. Johnson

Department(s):

Paper Science & Engineering

Research Mentor(s)

Marian G. McCord/Biomedical Engineering

Richard A. Venditti/Paper Science & Engineering

Title of Presentation:

Atmospheric Plasma Technology: Applications in the Paper Industry

 

 

The objective of this research was to evaluate the application of atmospheric plasma technology to processes in the paper industry.  Two areas were investigated, the first being the impact of plasma treatment on a de-inking process.  Photocopied and ink jet printed papers were treated with He and O2 plasma for five minutes.  These samples were subsequently re-pulped and then processed using a flotation de-inking cell.  Image analysis on the processed samples indicated that the plasma treatments discouraged the flotation of both the toner and ink.  The results suggest that the He/O2 treatment caused the surface of the toner and ink particles to be more hydrophilic, resulting in lower ink removal efficiency.  This may be exploited when doing wash de-inking, which depends on ink particles being hydrophilic. 

            The second part of the research studied the effect of plasma treatments pertaining to the penetration of liquids into paper.  Plasma treatments consisting of He and He/CF4 were applied in varying amounts to un-sized, un-filled bond paper.  Penetration Dynamic Analysis (PDA) was performed to examine the liquid absorption properties of the treated papers.  The results indicated that the plasma treatments acted as a sizing agent, decreasing water penetration into the paper.  The plasma treatments show promise in altering the water absorption properties of paper.  The potential for application of these treatments is important to the development of water and grease resistant papers.



 

 


 

Student Author(s): 

Peter G. Lam

Dave J. Frankowski

Department(s):

Chemical and Biomolecular Engineering

Research Mentor(s)

Richard J. Spontak/Chemical and Biomolecular Engineering

Ian Manners/Chemistry, University of Toronto

Xiao-Song Wang/Chemistry, University of Toronto

Title of Presentation:

Semicrystalline Block Copolymer Nanotubes Derived from the Polyferrocenylsilane Metallopolymer

 

 

Block copolymers are fascinating materials that continue to attract tremendous fundamental and applied attention due to their ability to spontaneously self-organize into a wide variety of mesoscale structures depending on factors such as composition/weight and repeat unit asymmetry. Commonly encountered morphologies include spheres, cylinders, bicontinuous channels and bilayers, which can exhibit long-range spatial order, as discerned from small-angle scattering and electron microscopy. Unlike most conventional examples of self-organizing polymers, however, asymmetric polyferrocenylsilane-b-polymethylvinylsiloxane (PFS-b-PMVS) diblock copolymers have also been shown to form nanotubes and rods at dilute concentrations in PMVS-selective organic solvents. Resultant nanotubes range in diameter from ~20-35 nm, depending on solvent conditions and PMVS crosslinking. The mechanism by which these nanotubes develop has remained elusive since their discovery, and their characteristics remain poorly described in the literature. It is known, for instance, that PFS homopolymer is a  semicrystalline material possessing a monoclinic lattice (2/1 helix) with unit cell dimensions of a = 1.32 nm, b = 0.61 nm and c = 1.37 nm. Selected-area electron diffraction (SAED) analysis of the PFS-b-PMVS nanotubes conducted in the present study reveals that the nanotubes likewise exhibit long-range order with scattering reflections that are surprisingly consistent with the crystalline structure of melt- and solution-crystallized PFS homopolymer films and fibers. These results indicate that the PFS section of the nanotube, which measures only 6.2 ± 1.2 nm thick, is semicrystalline. This example of macromolecular crystallization in such a nanoscale environment surpasses reports of crystallization in 25 nm block copolymer spherical domains and, as such, may be at least partially responsible for directing nanotube growth.



 

 


 

Student Author(s): 

Jonathan Leerkes

Brian M. Hoffert

Department(s):

Paper Science and Engineering

Research Mentor(s)

Richard Venditti/Paper Science and Engineering

Title of Presentation:

Wax Removal of Waxed Board during Recycling Using Emulsifying Agents

 

 

With the ever increasing recovered paper costs due to increasing foreign fiber market demands, the U.S. paper industry is seeking new methods to recycle old corrugated containers (OCC).  One source of OCC that is currently not being recycled is waxed OCC due to the problems occurring with the wax fouling  process equipment and with residual wax in the OCC downgrading the paper quality. One proposed solution to this problem is the addition of emulsifiers at elevated temperatures during repulping operations. The experiments conducted were to evaluate the removal of wax from OCC using two different emulsifiers at six different concentration levels. The waxed board was repulped at 3 percent solids for 20 minutes in a Waring blender. The pulp was then centrifuged for 10 minutes to extract the wax in the water medium from the slurry. Handsheets were then made and image analysis performed to determine the effectiveness of the emulsifiers on wax removal. 

 

 


 

Student Author(s): 

Nicholas C. Linn

Department(s):

Chemical and Biomolecular Engineering

Research Mentor(s)

George Roberts/Chemical and Biomolecular Engineering

Title of Presentation:

Chemical Recycling of Plastics Via Glycolysis

 

 

The manufacture of poly(ethylene terephthalate) (PET) for use in soda bottles produces over 4 billion lbs. of waste annually in the U.S.  These bottles can be physically recycled to PET fiber and strapping; however, FDA regulations prohibit the reuse of such low-purity PET in beverage containers because of possible contamination of the contents.  A chemical recycling step is required to achieve the necessary purity.  This research project aims to characterize the equilibrium of the melt glycolysis of PET as part of the development of an improved chemical, rather than physical, recycling process which will allow for the direct reuse of post-consumer PET waste in beverage-contact applications. 

            The glycolysis of PET is affected by contacting the polymer with ethylene glycol.  The ethylene glycol attacks the ester linkages and breaks down the polymer to produce low molecular weight oligomers.  Because the glycolysis reaction is reversible, understanding the equilibrium of the system is essential to achieving the desired conversion and reaction product in the chemical recycling process.  The reaction equilibrium of the glycolysis of PET is being studied using batch reactors in an oil bath at temperatures above the melting point of PET.  Products are analyzed using end group titration, allowing for the determination of the hydroxyl number and subsequent calculation of the equilibrium constant for the glycolysis reaction.



 

 

 

Student Author(s): 

Blake C. Lucas

Department(s):

Electrical Engineering

Research Mentor(s)

Hamid Krim/Electrical Engineering

Title of Presentation:

Road Detection in Multispectral Imagery through Nonlinear Statistical Classification

 

 

We propose a road detection algorithm for Multispectral satellite imagery on the basis of classifying data according to nonlinear statistical models. We first extract four principal components from a four band Multispectral image: luminance, saturation, greenness and NDVI (Normalized Difference Vegetation Index). Next, the ISODATA (Iterative Self-Organizing Data Analysis Technique) algorithm translates the data set into a high-dimensional graph comprising hyperellipsoids of Gaussian densities. The MinMax Cut algorithm then iteratively partitions the cluster graph into a binary tree. Each node in the tree is an aggregation of clusters called a niche. A calibration procedure identifies the desired feature by comparing each niche in the tree to a niche model of the feature. Finally, the classification procedure computes the niche membership probabilities for each pixel and decides which pixels resemble the target feature. The proposed algorithm provides an automated hierarchical approach to nonlinear statistical classification.

 

 


 

Student Author(s): 

Allison Marks

Kristen Efird

Courtney Horton

Jesse Parker

Jessica Smith

Department(s):

Biomedical Engineering

Research Mentor(s)

Gary Mirka/Industrial Engineering

Frank Abrams/Biomedical Engineering

Michael Boyette/Biological and Agricultural Engineering

Title of Presentation:

Creative Cycle Ergometer

 

 

 

Our objective was to develop a creative cycle ergometer that meets the needs of individuals with a diversity of disabilities.  Conventional exercise equipment generally does not accommodate individuals who have compounding disabilities.  Available equipment is costly.  The ergometer should be easy to get into, feel stable, be easy to adjust, and retail for under $1000.  Five hypothetical clients  with a range of disabilities have been assessed and researched for this purpose.  These individuals include a 400lb male with type II diabetes and poor eyesight, an elderly female stroke patient with limited right arm function, a male with diabetes and Parkinson’s disease, a young girl who is deaf and has type I diabetes, and finally, a male who is blind and has fluctuating weight problems. The design team broke the problem down into the following categories: display/controls, seat/track, and pedals.  Speech synthesis was used to convert tachometer data into audible information for the blind patient, and Braille was added to the resistance knob.  A durable chair was used to make the bike more stable.  Larger pedals make the exercise motion more fluid.  Handles add more support for all of the patients.  After receiving approval from the Institutional Review Board, four representative subjects tested the bike and provided feedback.  On a scale of 1 to 10 with 10 being the most positive, the subjects’ responses averaged their overall experience as an 8.  The visually impaired subject found the “talking” display a great asset.  The obese subject found the chair to be wobbly, but this should not be a problem if the bike is used on a surface with more friction, such as carpet.  The stroke subject had a unique case different from the competition guidelines, so the pedals on the ergometer were unsuitable; otherwise, the bike was easy to use for the stroke patient. While the bike is not an optimal solution for each hypothetical client, it is a workable solution for the clients as a whole.

 

1 These patients were specified by the 2004-2005 National Student Design Competition of the Rehabilitation Research Center on Accessible Medical Instrumentation of Marquette University and the University of Connecticut.



 


 

Student Author(s): 

Elijah H. Martin

Gregory C. Hahn

Department(s):

Nuclear Engineering

Research Mentor(s)

Mohamed A. Bourham/Nuclear Engineering

Title of Presentation:

Characterization of Arc Generated Plasma Interactions with a Liquid Metal Medium

 

 

Inertial confinement fusion is a promising new technology that is positioned to address the future energy needs of the world. Inertial confinement fusion is the process in which a fuel capsule with a core composed of deuterium-deuterium or deuterium-tritium is indirectly heated and compressed by means of heavy/light ion beams or high energy lasers to temperatures and pressures that will allow fusion to take place. An advanced design concept for ICF reactors is to use a circulating liquid barrier to protect the first wall of the target chamber. With the impaction of fusion generated plasma and radiations on the liquid barrier sputtering can occur causing particulate matter to enter the target chamber interior volume. In order to best engineer the design of the target chamber modeling plume characteristics of high energy-density arc-generated plasma interacting with a liquid metal media will be necessary. This experiment is designed to simulate this interaction by generating high energy-density plasma above a liquid metal pool. Collection substrates are assembled inside the test cell to allow for the collection of plume particulates for analysis using scanning electron microscopy, energy dispersion x-ray analysis, and particle counting and size distribution. Characterization of the generated plumes shape and size of evolved vaporized liquid metal particulates, particulate density and other important plasma parameters are studied in this research. Electrical and spectral data are obtained for each test, transient discharge, to obtain the plasma parameters including total power, impedance, electron temperature and density and identification of species.


 


 

Student Author(s): 

J. Jordan Massey

Department(s):

Biomedical Engineering

Research Mentor(s)

Juan P. Hinestroza/Textile Engineering, Chemistry & Science

Title of Presentation:

Antibacterial Self-Assembled Nanolayers

 

Electrostatic self-assembled nanolayers of functional polyelectrolytes are being deposited on cotton fabrics. Cationic cotton was produced by using 2,3,epoxytrimethylammonium chloride. Chitosan solutions were prepared by dissolving it into a 1wt% acetic acid aqueous solution.  Polystyrene sulfonate, polyethylene imine, polyallylamine hydrochloride, poly L glutamic acid and poly L lysine were prepared using 0.15M sodium chloride aqueous solutions.  Layers were deposited by sequentially dipping the substrates into the polycationic and polyanionic solutions with a rinse step in between. Confirmation of the cationization of cotton was made using acid dyes.  Evidence of the deposition of the nanolayers was determined using X-ray photoelectron spectroscopy and Fourier Transform Infrared Spectroscopy. Potential applications include hospital linens and bandages.

 



 

Student Author(s): 

Marc Mathews

Shane Miller

Joe Rittiner

Department(s):

Chemical and Biomolecular Engineering

Research Mentor(s)

Juan Hinestroza/Textile Engineering, Chemistry and Science

Title of Presentation:

Development of a Miniature UV-NIR Spectroscopy Apparatus to Detect  Chemical Warfare Agent Simulants on a Real Time Basis

 

 

Chemical weapons represent a severe threat to the health and safety of the free world, especially in this age of terrorism. Testing of protective equipment to combat chemical weapons is currently done by the Man-In-Simulant-Test (MIST). In this test, a man wears a protective suit and is placed in a chamber filled with a chemical agent stimulant, a biologically inactive chemical with similar physical properties to the chemical agent. It is then measured how much simulant penetrated the suit, and thus, the suit’s effectiveness can be determined. Currently, the amount of simulant is measured by absorbent pads, which can only measure the cumulative amount of simulant that passes through the suit. Therefore, real time data collection is not possible. In addition, the pads only absorb one chemical, methyl salicylate (MeS), so equipment testing with multicomponent mixtures is also not possible.

            A real-time detector system will be developed for use in testing of protective equipment. Ultraviolet-Near Infrared (UV-NIR) spectroscopy will be used to identify the concentrations of simulants inside the protective equipment on the order of parts per million. The use of absorbance spectroscopy allows the simultaneous concentration measurement of multiple components. Fiber optic cables will be used to carry the spectroscopic data streams. This allows the sample chamber to be placed inside the harsh testing environment, while leaving the sensitive spectroscopy equipment in a more accommodating location. Computer software will be used to calculate concentration figures from absorption readings, and to collect data. This detector will allow the collection of more complete and accurate concentration data, providing a better foundation for the design of protective equipment.



 

 


 

Student Author(s): 

Jessica H. McCoy

Department(s):

Industrial Engineering

Research Mentor(s)

Thom Hodgson/Industrial Engineering

Russell King/Industrial Engineering

Title of Presentation:

Integer Programming Algorithm in Fortran

 

 

 

Nearly every business makes frequent decisions concerning inventory distribution, warehouse location, manufacturing batch sizes, or budgeting – all with the end goal to minimize costs and/or maximize profits.  Many of these types of problems can be modeled and solved via integer programming.  In industrial applications, a typical optimization problem may have dozens to thousands of variables and constraints.  Any increase in computational efficiency benefits the client tremendously, and the applications of such a method reach as far as today’s global economy.

            A principal focus of operations research is the study of the allocation of scarce resources.  Different types of programming problems are used to model actual situations, and the most-studied is linear programming (where all constraints are constricted to be linear).  An important subset of linear programming is integer programming, where the decision variables are additionally restricted to be integers.  Several algorithms have been developed to specifically address this latter set of problems, as they are more difficult to solve than non-restricted linear programming problems.  The widely-used branch-and-bound algorithm allows the user to focus on optimizing a few variables while keeping the rest constant, cycling through all of the variables until optimization is complete.  Gomory cuts reduce the amount of computation necessary by trimming the feasible solution space, thereby restricting the iterated optimal solution.

            I worked with Professors Thom Hodgson and Russell King to develop an algorithm in Fortran to utilize both Gomory cuts and a new class of cuts to solve integer programming problems.  The aim of the experimental algorithm is to trim the feasible solution space of a problem until the only point remaining is the integer solution.

 

 


 

Student Author(s): 

Daniel W. Mellinger

Department(s):

Mechanical and Aerospace Engineering

Research Mentor(s)

Larry M. Silverberg/Mechanical and Aerospace Engineering

Chau M. Tran/Mechanical and Aerospace Engineering

Title of Presentation:

Numerical Analysis of the Basketball Shot

 

 

Millions of people play the game of basketball and yet no comprehensive study of the game has ever been done.  When the ball leaves the shooter’s hand, there is no luck as to whether the ball will go in or not. The outcome can be determined with mathematics.  In this project, a computer code simulates the dynamics of a basketball shot taken from any location on the court.  The code handles any combination of bounces off of the rim and backboard, rolling and sliding on the rim and backboard, the changing backspin of the ball, and even the uncommon swirling of the ball.

            The program was then run tens of thousands of times for balls released with different initial speeds, angles, and rates of spin from about 30 different positions on the court.  The data generated was used to analyze the shooter’s statistical characteristics. The best shot was found for each spot on the court. The probability of the best shot was found. It was found where on the court the bank shot is most effective.  The data revealed where it’s most advantageous to place backspin on the ball by flicking the wrist and where it’s helpful to shoot a floater (no spin).  

            All of this data is now being distilled for display in a poster. The poster targets the high school audience.

 



 

 


 

Student Author(s): 

Jared D. Morris

Department(s):

Paper Science and Engineering

Research Mentor(s)

Richard Venditti/Paper Science and Engineering

Orlando Rojas/Paper Science and Engineering

Title of Presentation:

The Fundamental Role of Surfactants in the Removal of Toners from Recovered Paper

 

 

Mixed office waste is an abundant inexpensive recovered paper that can provide high quality fibers if properly recycled. It is currently underutilized due technical issues regarding recycling.   One of the major issues in recycling MOW is that it is very difficult to detach toner type inks from the surface of the fibers.  Undetached toner is not typically removed from the fibers and remains in the recycled product, downgrading its quality.  This research project involved examining three different types of surfactants and their effects on removing inks from MOW.    A penetration dynamics analyzer was used to determine the effect that the surfactants had on water penetration into the sheet.  Additionally, a standard printed copy paper was pulped in the presence of the different surfactants to determine the effect on toner size and detachment after pulping.  This project has resulted in a better understanding of the role of surfactants in the deinking of toner containing papers.



 

Student Author(s): 

Amika R. Olchovik

Department(s):

Biomedical Engineering

Research Mentor(s)

Juan P. Hinestroza/Textile Engineering, Chemistry & Science

Title of Presentation:

Diffusion Coefficient of Methanol Through Silk Fibroin Polymer Solutions

 

 

The diffusion coefficient of methanol through silk fibroin polymer solutions was determined by monitoring the coagulation process using a video camera.  Digital imaging software was used to follow the boundary of the coagulation front through a capillary.  The coagulation experiments were performed inside Pasteur’s pipettes of 1.8 mm in diameter. Polymer solutions were loaded into the lower section of the capillary using a vacuum bulb. Small amounts of methanol were added to the top of the pipette.  Preliminary experimental results were in quantitative agreement with Fickean diffusion theory.  Future work will analyze the effect of polymer concentration on the diffusion process.



 

Student Author(s): 

Kristy L. Perez
Jason Swingler
Brian Thompson
Stephen Wohlers

David Young

Department(s):

Nuclear Engineering

Research Mentor(s)

Orlando Hankins/Nuclear Engineering

Robin P. Gardner/Nuclear Engineering

Charles W. Mayo/Nuclear Engineering

Title of Presentation:

Small Reactor for a Remote Location

 

 

As environmental consciousness increases, so does the attractiveness of nuclear power.  In remote locations, such as islands or arctic regions, electric power is often difficult to produce and very expensive – in both monetary and environmental costs. As technology advances, so does the capability to provide such locations with cleaner, more affordable power. Selecting a hypothetical Alaskan town of approximately 2500 people, a small nuclear reactor of 135MWth producing 50MWe has been designed to provide power for heating, electricity, and to support industry.  To prove not only is nuclear power viable, but in fact the best solution to meeting the power needs of these small, remote communities, major aspects of nuclear reactors such as neutronics, thermodynamics, radiation shielding, burnup and efficiency, along with feasibility and cost effectiveness have been researched and developed.  The reactor would be housed underground. Monte Carlo MCNP code has been used to calculate heat deposition, neutron flux, power dissipation, and dose outside the core. Two core designs were considered, a 4.0m high by 0.83 m width and a 1.5m high by 1.2m width, with both designs maintaining same cycle burnup.  Exploration of other possible sources of energy, and different types of nuclear reactors has also been completed; leading to an explanation of the selection process and of the final decision – a Liquid Sodium Cooled Fast Breeder Reactor.  Highlights of this design include a modular design, enhanced safety features, little human interaction and support during operation for a 10-year core life.



 

Student Author(s): 

Ahmad Sadri

Department(s):

Civil Engineering

Research Mentor(s)

Francis L. de los Reyes, III/Civil Engineering

Title of Presentation:

Effect of Lipids and Temperature on Foaming in Lab-Scale Activated Sludge Reactors

 

 

A problem at many wastewater treatment plants is the accumulation of thick brown foam on the surface of aeration basins. The foam is associated with large numbers of actinomycete microorganisms (nocardioforms), which float on the surface of aeration basins and have access to floating wastewater substrates such as oils, fats, and greases. Previous studies have suggested that nocardioforms use lipase enzymes to consume fat, and that lipase activity was very sensitive to temperature variation. The goal of this project was to determine the effects of varying operating temperatures on the degree of foaming. Two lab scale sequencing batch reactors (SBR) were set up; one was operated at a constant temperature while the other was operated at steadily increasing temperatures. Equal amounts of vegetable oil were added to both reactors every day in addition to synthetic wastewater. Foaming potential / stability tests and solids tests were performed periodically. The average water temperature of the control reactor was 25˚C. The temperature in the experimental reactor could only be increased to about 27˚C, even when two temperature controllers were set to their highest value of 32˚C. It was decided to run the control reactor at 25˚C and the experimental reactor at 27˚C. On average, the foaming potential, foaming stability, and solids concentration in the experimental reactor were greater than in the control reactor. A distinct relationship between temperature and mixed liquor suspended solids (MLSS) concentration was observed.

 



 

Student Author(s): 

Heather L. Saladin

Rachel C. Evans

Jonathan W. Ham

William R. Potter

Tih-Hong Wang

Department(s):

Biomedical Engineering

Biological Engineering

Research Mentor(s)

Ola Harrysson/Industrial Engineering

Denis Marcellin-Little/Veterinary School

Title of Presentation:

Development of Apparatus for Testing the Efficacy of Canine Stifle Joint Braces Using Rapid Prototyping

 

 

 

Rehabilitation of canine stifle joint injuries requires the use of braces and/or surgery. Current rehabilitation braces are designed non-specifically for treating a large range of patient sizes and stifle joint injuries. The lack of specific brace designs causes unpredictability in rehabilitation applications. Currently, selections of braces are done on trial basis. There is a need by veterinary professionals for a testing device that mimics the design and function of the canine stifle joint.

            Computed Tomography (CT) scans were obtained from the left, rear leg of a healthy adult Doberman. The biomodeling software, Mimics, was used to isolate the soft tissue, tibia/fibula, and femur to then create 3D stereolithography (STL) files. In another software program, Magics, the comprised facets were recalculated. The subsequent file was processed using Geomagics to create a 3D NURBS surface allowing the STL files to be converted into Solidworks file format. In the distal femur, a space was created for insertion of a linear displacement variable transducer (LDVT), and the femoral head and distal portion of the tibia were removed in Solidworks. The final STL files of the tibia/fibula and femur were rapid prototyped using stereolithography and replicated using an epoxy-fiberglass composite with bone powder. The soft tissue was constructed using a similar method but with vulcanized rubber. The collateral and cruciate ligaments were simulated with the use of high density polyethylene fiber, while the femoral head, lower tibia/fibula, and foot were machined from aluminum. The created leg was then attached to a fabricated base that allows vertical movement.

            The testing apparatus simulates and records, using the LDVT, normal and abnormal displacement in the stifle joint during full range of motion. The data was then used to quantitatively determine the effectiveness of various braces in minimizing drawer displacement in the stifle joint.



 

Student Author(s): 

Jordan B. Schwarz

Department(s):

Mechanical and Aerospace Engineering

Research Mentor(s)

Fred R. DeJarnette/Mechanical and Aerospace Engineering

Title of Presentation:

Navigation and Localization of the Mars Tumbleweed Rover

 

 

Mars Tumbleweed is a proposed rover, shaped like a giant ball, that would explore the surface of Mars by rolling around it, propelled by the planet’s winds.  To support Tumbleweed’s science missions, an accurate track of the rover’s course is needed. On Earth, accurate tracking is accomplished using the Global Positioning System array of satellites, but on Mars, no equivalent system exists.  A host of possibilities for tracking the rover exist;  however, challenges to the accuracy and viability of these methods are present as well. This paper surveys the available and potential tracking techniques and evaluates them for their merit and applicability to Mars Tumbleweed, given its unique geometry and goal of being a low-cost rover.  Based on the evaluation of these techniques, it is recommended to use radiometric ranging between the Tumbleweed and Mars orbiters in conjunction with high-accuracy gyroscopes on board the Mars Tumbleweed to provide primary guidance and positioning.

 



 


 

Student Author(s): 

Tyler M. Schweitzer

Department(s):

Nuclear Engineering

Research Mentor(s)

Mohammed A. Bourham/Nuclear Engineering

Ronald Berliner/Nuclear Engineering

Ayman I. Hawari/Nuclear Engineering

Title of Presentation:

Stepper Motor Control System for Neutron Defractometer

 

 

 

The project of building the control system for the stepper motor control on the neutron defractometer consisted of three main stages.  The first stage was learning how to program in a computer language called Java.  Java is the computer language used for writing the program to control the movements of the stepper motor.  The next phase includes designing and assembling the interface panel.  This panel consists of a power supply, motor, and 3 connector ports connecting to the stepper motor and a computer.  Each part of this panel was assembled properly, by connecting all of the necessary parts through a series of wires.  The final stage of this project is to actually write the program that the motor on the control panel will use to control the stepper motor.  This program will allow the stepper motor to turn to a precise angle, giving the operator full control of the defractometer. 



 

Student Author(s): 

Jonathan E. Semones 
Abby Griffith
Jason Vanduyn
Jess Bardin

Laural Flythe

Department(s):

Materials Science and Engineering

Industrial Engineering

Research Mentor(s)

Denis C. Cormier/Industrial Engineering

Michael J. Rigsbee/Industrial Engineering

Title of Presentation:

Process Development of Titanium Aluminide (γ) Using the 

Arcam S12 Electron Beam Melting (EBM) Machine

 

 

Recently there has been much interest in implementing a γ-TiAl alloy in aeronautical applications.  Another area of interest is in creating metal details directly from metal powder by use of the Arcam S12 Electron Beam Melting (EBM) machine.  Our group has meshed these two areas of research to use EBM to make a γ-TiAl alloy from a powder of composition Ti-47Al-2Cr-2Nb.  Optical microscopy, X-ray diffraction, SEM, ICP, and hardness measurements were performed to characterize the alloy created in the Arcam.  A large loss in the amount of aluminum and chromium was measured in the metal detail from the ICP results, which takes the alloy out of the γ phase and puts it into the lamellar α2 + γ phase.  These results were complimented by the X-ray diffraction data in that both α2 and γ phases were present.  The diffraction on the initial powder showed that it was not in the γ phase either.  A film was deposited on the inside of the machine during the formation of the part.  X-ray showed the film to be in the γ phase, and would account for the loss of aluminum in the part.  The average hardness of the processed alloy was measured to be 427 DPH.

 



 

 


 

Student Author(s): 

Scott A. Shore

Department(s):

Biological and Agricultural Engineering

Research Mentor(s)

Kevin Keener/Food Science

Jerome Cuomo/Materials Science and Engineering

Brian Sheldon/Poultry Science

Title of Presentation:

Atmospheric Plasma Treatment to Eliminate Food Pathogens

 

 

Loss of work due to food born illness is estimated by the CDC to cost $6.7 billion annually. This loss shows a need for better food treatment systems. Atmospheric plasma had been used by the military for biological decontamination. Atmospheric plasma offers many desired qualities in a food treatment system. Atmospheric plasma is a low cost and efficient process with  no environmental impact. For these reasons, this technology may have potential in pathogen removal from foods. Gas composition of the plasma is believed to be the primary controlling factor in reducing pathogen levels. Two different plasma systems were used to investigate the effect of gas composition. The first system was a dielectric barrier discharge (DBD) chamber. The initial tests used the DBD chamber to treat Listeria innocua inoculated on agar plates at 10^6 forming units per milliliter (cfu/mL). Three different gas compositions were tested: Helium, Helium/Nitrogen, and Helium/Nitrogen/Oxygen. Only the gas combination with oxygen consistently achieved a 10^6 reduction of the Listeria in as little as 1.25 minutes. Other gas compositions were able to achieve 10^6 reductions but in longer times. The Helium plasma could achieve a 10^6 reduction after 15 minutes of exposure and the Helium/Nitrogen mixture after 5 minutes of exposure. The other system investigated was a Tepla pen system. The Tepla pen is a portable, handheld plasma generator and applicator. Agar plates were inoculated with a Salmonella cocktail at 10^7 cfu/ml and then swept under the Tepla pen. The Tepla pen produced no growth bands between 1 and 7 mm wide. The addition of oxygen to the Tepla pen plasma resulted in the larger bandwidths with no growth. Both systems were able to completely remove pathogens in localized areas. A minimum treatment time of 0.41 seconds was observed for the Tepla pen system.



 

 


 

Student Author(s): 

Jacob E. Singer
Caitlin C. Carpenter
Kristen A. Meador
David H. Wagner, IV

Kristal O. Wilson

Department(s):

Biomedical Engineering

Research Mentor(s)

Frank Abrams/Biomedical Engineering

Michael Boyette/Biological and Agricultural Engineering

Title of Presentation:

Wheelchair Adaptable Examination Table

 

 

The transfer of wheelchair-bound patients to examination tables for treatment or routine examinations presents injury risks to the patient and caregivers involved.  Injury risks to patients include broken bones, joint dislocation, and skin abrasion, while caregivers face an increased risk of back injury.  Utilizing patient slings reduces injury risks to caregivers and patients, but this practice is often unsettling and dehumanizing to patients.  Our sponsor, Dr. Martin, has proposed a wheelchair adaptable examination table in which a modified wheelchair can be rolled onto and coupled with a modified examination table to eliminate the need to transfer the patient from one location to another.  A 2004 Senior Design team developed a locking mechanism between the modified wheelchair and the examination table, along with additional wheelchair modifications to allow the wheelchair to recline.  The focus of this year’s project was the design of a new automated lift mechanism for the examination table with the capability to lower below the height of the wheelchair seat and reach a range of examination heights based on the preference of the doctor.  The new lift, based on the concept of a hydraulic jack, utilizes a hydraulic cylinder linked to an angled arm to convert linear motion to rotary motion.  To address safety concerns, the lift was designed for a 2000 lb load with support arms for lateral stability and a fail-safe feature to protect against hydraulic failure.  The new lift mechanism for the wheelchair adaptable examination table contributes to the solution to problems associated with the transfer of wheelchair-bound patients.

 



 

 

 

Student Author(s): 

Kelley L. Spence

Department(s):

Paper Science Engineering

Research Mentor(s)

Orlando Rojas/Paper Science Engineering

Title of Presentation:

Development of Cellulose Thin Films for Studies in Surface Chemistry

 

 

Cellulose, the most abundant polymer on the planet, is an important alternative as a precursor for macromolecular synthesis and a thorough understanding of its interfacial behaviors is largely needed. In this study we developed thin films of cellulose with different crystallinities and morphologies to mimic more closely that of natural cellulose and to study its effects on surface behavior, such as adsorption of polymers and reactions with enzymes, etc.

            Crystalline cellulose monolayers were successfully prepared by the self assembling of a cellulose-thiol derivative on Au substrates and characterized by FTIR and AFM. The resulting films were compared with those obtained by spin coated techniques using silica surfaces as substrate. The utility of these systems is discussed in view of ongoing research in our department.



 

 


 

Student Author(s): 

Mark E. Stuenkel

Department(s):

Electrical and Computer Engineering

Research Mentor(s)

Doug Barlage/Electrical and Computer Engineering

Title of Presentation:

The Design and Analysis of a Platform to Test a Novel GaN MOSFET’s Ability to Amplify at Frequencies Approaching the “Terahertz Gap”

 

 

Physical limitations such as size and carrier transit time prevent the development of active electrical devices that operate in the frequency range from 300GHz to 5THz.  The common technique of decreasing the size of a transistor’s base or gate to increase its maximum operational frequency has almost reached its limit.  With current gate lengths being on the atomic scale, further decreasing of gate lengths proves to be almost impossible.  Researchers at North Carolina State University have proposed and built a device (GaN MOSFET) that uses negative differential resistance effects as opposed to traditional methods to provide amplification up to a theorized frequency in this “Terahertz Gap”.  My project involved the design and analysis of a novel test platform to be used in the extraction of the amplification properties of this device, since such a platform currently does not exist.  In the analysis portion of my project, I characterized the reflection coefficient in terms of the various surface resistances and semiconductor dopings in order to both provide a means of calibrating the test platform and determining what reflection would be expected in normal operation.

 



 

Student Author(s): 

Christopher A. Sutay

Department(s):

Biomedical Engineering 

Research Mentor(s)

Glenn M. Walker/Biomedical Engineering

Title of Presentation:

A Novel Electrostatically Actuated Elastomeric Microfluidic Valve

 

 

Microfabrication advances have allowed the integration of fluid handling components into microscale lab-on-a-chip systems.  Valves and pumps within these systems should be designed to minimize damage to sensitive biological components (e.g., cells, proteins, etc.) within the chip.  One attractive approach is to use elastomeric membranes for pumps and valves.  However, current methods utilize cumbersome macroscale pneumatic hardware to inflate the elastomeric bladders for valve actuation.  The goal of this project is to use electrostatic forces to actuate the elastomeric valves, thus eliminating the need for bulky external equipment.

 

Using the process of thick film soft UV lithography, a multilayered microfluidic device was created in the Tiny Biotools Lab (http://www.bme.ncsu.edu/labs/tbl ).  A base support structure composed of 10 micron thick SU-8 photoresist was deposited on a silicon wafer.  Circular Cr electrodes, 1 mm in diameter, were patterned in depressions within this support structure using physical vapor deposition.  An elastomeric polymer, polydimethylsiloxane (PDMS), was used to create a 30 micron thick membrane with an identical electrode scheme, seated above the support structure layer.  A valve channel layer was also created out of PDMS to allow fluid flow over the membrane, with valve seats that block flow situated above the actuated area.  In the assembled device, a potential will be created between the two electrodes to cause an electrostatic attraction.  When the valve actuates, the membrane Cr electrode will be attracted to the Cr electrode at the base of the support layer, creating a downward deflection of the membrane, and subsequent fluid flow beneath the valve seat.

 

Voltage values and membrane deflections have been optimized, taking into account the boundary conditions of the membrane as well as the mechanics of the materials used.  Future versions of this project will include three valves in series acting as a peristaltic pump.



 

Student Author(s): 

Vesna Tosanovic

Department(s):

Wood and Paper Science

Research Mentor(s)

Orlando Rojas/Wood and Paper Science

Title of Presentation:

Monitoring Cellulase Activity by the Quartz Crystal Microbalance

 

 

 

Cellulose and hemicelluloses can be converted to soluble sugars by enzyme hydrolysis.  Cellulases and hemicellulases are some of the enzymes of current commercial significance for this and other applications. In this investigation we examined the interfacial  behavior of cellulose active enzymes on model cellulose substrates by using a piezoelectric sensor, the Quartz Crystal Microbalance with Dissipation monitoring (QCM-D). 

            We showed that QCM-D allows monitoring (in situ and real time) of  enzyme activity by measuring the resonant frequency of the crystal.  In a typical experiment an increase in the crystal/substrate resonant frequency was observed after the initial binding of the enzyme to the substrate. This behavior indicates a reduction of the mass of the substrate as a result of film degradation.  We demonstrate the  potential of QCM-D to monitor and quantify the detailed kinetics of enzyme activity and to probe the effect of variables such as enzyme concentration, temperature, pH and mixing conditions during incubation.



 

 


 

Student Author(s): 

Diep Vo

Department(s):

Materials Science and Engineering

Research Mentor(s)

Jag Kasichainula/Materials Science and Engineering

Title of Presentation:

Characteristics of Diamond on Lithium Niobate Substrate

 

 

The layer structure of LiNbO3/diamond can be used in various applications such as communication systems, TV sets, surface acoustic wave devices at high frequency (2-5GHz), and radar signal processing. The objective of this research is to characterize diamond films grown on lithium niobate (LiNbO3).  Diamond is used because it has high acoustic wave velocity. Diamond is deposited on LiNbO3 by microwave plasma chemical vapor deposition (MPCVD) at lower temperature, between 650-700 oC, to lower the loss of lithium and to reduce thermal stresses. The differences between LiNbO3 and diamond on atomic bonding and crystalline structure are responsible for poor quality of diamond films. The low temperature of deposition of diamond on lithium niobate is responsible for amorphous carbon or graphite to be incorporated in the diamond film.  The goal is to understand the characteristics of diamond on lithium niobate by using x-ray diffraction, scanning electron microscopy (SEM), RAMAN spectroscopy, and electrical resistivity.



 

 


 

Student Author(s): 

John D. Waldrep
Scott R. Broderick

Ryan A. Mayer

Department(s):

Materials Science and Engineering

Research Mentor(s)

Joachim Lewerenz/Materials Science and Engineering

Title of Presentation:

High Voltage AC Corrosion in Underground Cables

 

 

 

This project involves corrosion studies under high voltage AC conditions for underground aluminum power delivery systems. The performance of power distribution terminals of Tyco Electronics and a competitor are compared. The terminal electrically connects several aluminum cables by pinning  them with aluminum set screws to a common aluminum block. The primary cause of failure is corrosion due to exposure to water. The competitor’s model is encased in a rubber housing that must be cut to form a friction fit with the inserted wire. Tyco’s design uses a silicone gel to create a compressive seal. The goal of the investigation is to assess corrosion behavior under conditions closely related to the operating environment. Due to the non-linearity of the electrochemical processes at high voltage and current, an empirical approach is necessary that has been complemented by more fundamental electrochemical research. Experiments involve corrosion studies of submerged terminals with and without housing under high AC voltage, physico-chemical analyses of corroded areas and potentiostatic model electrochemistry. Results show that advanced corrosion in the competitor’s model is effected by possible installation errors whereas such problems are minimized by Tyco’s design. As a second main result, Tyco’s tin-coated block has been found to exhibit strongly reduced corrosion at both, terminal block and wire. Cyclic voltammetry indicates higher resistance to corrosion for the tin-coated material evidenced by delayed onset of anodic currents with potential. In addition to practical considerations, the electrochemical model experiments indicate that each of Tyco’s modifications has improved corrosion resistance.



 

 


 

Student Author(s): 

Brandon Williamson
Greg Hogshead

Kelly Irving

Department(s):

Materials Science and Engineering

Research Mentor(s)

Richard Spontak/Materials Science & Chemical Engineering

Title of Presentation:

Improving the Barrier Performance of Multilayer Print Blankets

 

 

Multilayer print blankets used in the printing industry currently suffer from damaging permeation of organic and inorganic liquids during operation and cleaning. The objective of this project is to identify strategies by which the barrier performance of the blankets can be improved without sacrificing the overall design specifications and processing protocol of the blankets. The project employs a multisolution approach, wherein different types of barriers to permeation have been systematically introduced into the multilayer. In the first strategy, a layer of permeation-resistant polymer is introduced. These polymer films consist of either a semi-crystalline polypropylene or poly(ethylene-co-octene), which exhibit vastly different crystallinities. The second approach incorporates inorganic nanoparticulates into the multilayer design. Nanoparticulates with a very small aspect ratio (plate-like) have shown to be promising in previous research to enhance barrier efficacy, and so organically-modified montmorillonite clay has been examined. Alkyl-terminated fumed silica, a spherical particulate, has also been investigated for comparative purposes, since both nanoparticulates serve as impermeable obstacles. Lastly, we have explored the change in barrier performance afforded by thin inorganic, contiguous layers of SiOx and Au/Pd. Parameters that have been systematically varied during this project include polymer crystallinity, additive concentration, and coating thickness. Permeant uptake testing, also called "swell" testing, has been used to examine the nanoparticulate-modified samples. The sample geometry of the polymer and inorganic-coated samples does not allow for the use of swell testing, and so FTIR-ATR has been used for measurement purposes. From these methods, the diffusion coefficient (D) and solubility (S) could be extracted to facilitate comparison of the different methods of barrier improvement examined here. Quantitative permeation comparison of these options provides us with a direct method by which to (i) determine the best barrier solution and (ii) suggest viable avenues for future research in this important industry.

 


 

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Last modified February 2005 by Sharon E. Hunt, WordHunting