The 16th Annual

NC State University
Undergraduate Research Symposium

 

Engineering and Technology

Abstracts

 

Abstracts are listed in alphabetical order by the last name of the corresponding author.

 

 

 

 


 

 

 

Student Author(s): 

Abrecht, David G.

Department(s):

Wood and Paper Science

Research Mentor(s)

Hasan Jameel/Wood and Paper Science

Title of Presentation:

Effect of Cellulose Crystallinity Modification on Enzymatic Hydrolysis Rates

 

 

The mercerization of fully-bleached hardwood and softwood fibers was performed to examine the effect of fiber crystallinity on enzymatic hydrolysis. Comparison testing between hardwood and softwood was first carried out to determine major differences between fiber classes. Fibers were mercerized at 0, 3, 5, 8, 12, and 18% NaOH concentrations, washed to remove causticity, and hydrolyzed with cellulase complex and beta-glucosidase. Crystallinity was measured by X-ray diffraction and an index was calculated based on Clark-Terford method. Hardwood and softwood fibers were then refined for 1500 revolutions in a PFI mill, mercerized at the same concentrations and hydrolyzed to determine the effect of improvements in fiber surface area. Mass loss during hydrolysis was found to increase linearly with reductions in crystallinity index at high mercerization concentrations, but at low concentrations mass loss increased much more rapidly. Mass loss during hydrolysis was found to correlate strongly with the loss of mass during mercerization, despite correction to 1 oven-dry gram of fiber before hydrolysis began. This suggests that crystallinity is not the only factor affecting hydrolysis rates, or that changes in crystallinity may be a secondary effect. Refined samples showed improvements over non-refined samples at low mercerization concentrations but not at high mercerization concentrations, as expected.

 


 

 

Student Author(s): 

Attarian, Adam

Department(s):

Electrical and Computer Engineering

Research Mentor(s)

H. J. Trussell/Electrical and Computer Engineering

Title of Presentation:

The Feasibility of Illuminant Estimation in Hyperspectral Images Using Known Reflectance Values

 

We examine the feasibility of estimating the spectral characteristics of an illuminant from the reflectances of known objects. We determine the number of known reflectances needed to make an estimate using lagrangian minimization and projection onto convex sets (POCS). Working in a 31 dimensional space spanning 400-700nm, we find the useful dimensionality to be substantially lower by examining the eigenvalues of the covariance matrix associated with the known reflectances. Using basis functions based on optical filters, we are unable to match the relatively non-smooth D65 daylight illuminant, though believe that smoother spectral illuminants would provide better results. The POCS method is discussed, and explanations presented for the error in data fits.

 

 

 


 

 

 

Student Author(s): 

Belvin, Brian

Griffin, Jennifer

Reynolds, Brandon

Viscuso, Addie

Department(s):

College of Ag and Life Sciences

Research Mentor(s)

Ratna Sharma/Ag and Life Sciences

Title of Presentation:

Semi-Automated System for Enzymatic Production of Biodiesel

 

 

Growing environmental and national security concerns regarding diminishing fossil fuels have highlighted the need for exploring renewable alternatives like bioethanol and biodiesel. The goal of this research was to design and build a system employing an environmentally friendly and economically feasible conversion approach to produce biodiesel from oil. Current methods of converting oil to biodiesel involve harsh chemical catalysts in the oil-methanol transesterification reaction leading to undesirable and environmentally harmful by-products. An alternative conversion method, that requires in-depth investigation, involves the use of whole cells or lipase enzymes as the catalyst. However, the cost of producing and purifying enzymes poses a drawback for their use. Immobilizing the enzymes allows their re-use thus making the process economically feasible as well as environmentally friendly. This research investigated immobilization of lipases as well as fungal cells to produce the needed enzyme. The fungus, Rhizopus oryzae (ATCC-34612) that can be maintained on agar slants, was grown and immobilized on foam biomass support particles (BSP) in liquid media. R. oryzae continually produces lipases during growth, therefore reducing recurrent enzyme purchase cost. However, cell immobilization resulted in several challenges related to inhibition of growth by methanol, choice of media to promote lipase production, growth conditions, low enzyme activity, and conversion rate thereby hindering success. Immobilization of lipases, in calcium-alginate beads, to induce transesterification revealed low transesterification rates. The results of this project indicate that although a semi-automated biodiesel production system would be suitable for use with immobilized cells or enzymes, future studies on factors like increasing alcohol tolerance of the microorganism involved, lipase activity and stability, source of the purified enzymes, and effect of methanol on enzyme activity need to be explored for this approach to be commercially successful.

 

 


 

 

Student Author(s): 

Burton Jr., Ronald R. 

Krishnan, Arjun

Shankar, Ravi

Department(s):

Materials Science Engineering Fiber

Polymer Science

Research Mentor(s)

Tushar K. Ghosh/Fiber & Polymer Science

Richard J. Spontak/Materials Science Engineering & Chemical and Biomolecular Engineering

Title of Presentation:

Tailoring Properties of Electroactive Polymers Through Concentration of Midblock-Selective Solvent: A Route to High-Performance Electroactive Polymers from Renewable Resources

 

 

The concentration of midblock-selective solvent has been shown to dramatically affect the electrical and mechanical properties of poly[styrene-(ethylene-co-propylene)-styrene] (SEPS) triblock copolymers. In this study, we investigated the impact of replacing an aliphatic-rich mineral oil (MO) with a more complex and biologically degradable oligomeric solvent: vegetable oil (VO). Specimens containing mixed a mixed MO/VO solvent starting at 40 wt% VO have been analyzed. Electrical stimulation tests measured the areal strains achieved upon actuation and the dielectric breakdown field of each sample. In addition, mechanical measurements of tensile, compressive and hysteric stress elucidated the effect of solvent type on the elastic modulus of the samples. Quantitative analysis of these data revealed a direct impact on the elastic moduli of the samples: an increase in the concentration of VO from 40 to 70% resulted in a marked increase in the elastic modulus. The effect of solvent quality on electroactuation properties will also be presented.

 

 


 

 

Student Author(s): 

Chavis, Regina

Pickett, Carrie

Siddiqui, Sana

Jones, Randall

Department(s):

Biological and Agricultural Engineering

Research Mentor(s)

Sanjay Shah/Biological and Agricultural Engineering

Title of Presentation:

Development and Evaluation of a Pilot-Scale Biofilter/Heat Exchanger System for Improvement of Livestock Air Quality

 

 

Hog production is an integral part of the economy in North Carolina. As the population continues to grow and sub-divisions expand into the countryside, air quality becomes a key issue of contention between hog producers and their neighbors. Systems that process pollutants using organic materials known as biofilters may be a promising resolution for this emerging problem. While biofilters have been proven to enhance air quality, lack of regulations and the reluctance of producers to incur additional expenses have stunted their acceptance in the U.S. The objective of this research was to develop a pilot-scale biofilter coupled with a heat-exchanger to evaluate the potential of saving energy in conjunction with improving air quality. Ammonia is a major component in hog house emissions; therefore the system was designed to primarily trap this compound. The biofilter consisted of an insulated wooden structure packed with a 60/40 mixture of composted poultry litter and woodchips. A corrugated, aluminum pipe served as the heat exchanger and was placed in an s-like fashion through the center of the media. Two blowers were installed; one drew air from the hog house through the media for filtration and the other drew fresh air through the heat exchanger. The system operated for one week and pressure, temperature, and relative humidity were measured. Ammonia removal efficiency was measured using two acid scrubbers. The biofilter's average ammonia removal efficiency was 61%. At an airflow rate of 1.35 m3/min, tempering the nighttime fresh air in the heat exchanger increased its temperature by 1.4ºC and reduced relative humidity by ~ 5%. The potential energy savings over a 12 hour period was 0.03 m3 however; the drier air would make cold-weather ventilation more efficient.  Implementing this may offer both environmental and economic rewards.

 

 

 

 


 

 

Student Author(s): 

Cline, Stephen W. 

Department(s):

Electrical and Computer Engineering

Research Mentor(s)

Michael J. Escuti/Electrical and Computer Engineering

Title of Presentation:

Optical Enhancement Studies on Liquid Crystal Polarization Grating Projection Schemes

 

 

As the demand for high brightness, high contrast, portable video-display devices becomes more prominent, new projector technologies must be developed to overcome the inherent limitations of current technology. Projection displays based on a novel switchable diffraction grating (called Liquid Crystal Polarization Gratings, LCPGs) are one of the most promising solutions, because it eliminates the need for polarizers. Since the operational principle of this novel LC microdisplay is substantially different from all previous LC on Silicon (LCOS) devices, a new optical subsystem must be optimized for it. The focus of this research project is to improve the optical efficiency and brightness of this novel projection display technology. The central problem being solved is that while the diffractive microdisplay works best with collimated light, the most relevant light sources are only partially collimated. Therefore an optimized design of the lenses, prisms, and aperture-stops is necessary to minimize light loss between the light source and the microdisplay. Our approach to solving this is to use the principles of optical engineering and the commercial ray-tracing software TracePro(R) to collimate the light with as few losses as possible. The system will be an advanced way of manipulating light in a Schlieren projection system that will enable a brighter and more power efficient device than the LC projection display systems that are currently available.

 

 

 


 

 

 

Student Author(s): 

Coleman, Leslie S.

Berk, Lindsay K.

Woock, Jeremy D.

Department(s):

Materials Science Engineering

Research Mentor(s)

Carl C. Koch/ Materials Science Engineering

Title of Presentation:

Bimetallic Armor Plate Fuel Economy in Aircraft by Decreasing Drag

 

 

The purpose of this senior design project, sponsored by ATI Allvac, is to design a bimetallic armor plate. The ultimate goal is to replace the current K12®; dual phase armor plate, manufactured by Allegheny Technologies, with a lighter weight and more cost efficient product. The armor plate was created by roll bonding two metals created at Allvac’s facility to protect military equipment from projectiles. The first metal was a 13-8 Mo Supertough®; stainless steel alloy and the second was a modified M50 tool steel. The roll bonding was conducted at two austenizing temperatures, 2075ºF and 2200ºF, and experienced two thickness reductions of 75% (final thickness ~¼ inch) and 50% (final thickness ~½ inch). Ageing was performed at two temperatures, 1000ºF and 1050ºF, to evaluate effects on either material at different temperatures. Samples roll bonded at 2200ºF experienced cracking and plate separation during heat treatment while the samples roll bonded at 2075°F remained mostly intact. Hardness testing and metallurgy was conducted on both as-rolled and heat treated samples. The average hardness for the M50 side of the plate at heat treatments of 1000ºF and 1050°F were 63.9 and 64.7 HRC, respectively. Hardness values at heat treatments of 1000ºF and 1050°F were 42.2 and 41.9 HRC, respectively, for the 13-8 Mo Supertough®; side. Optical micrographs revealed a tempered plate martensitic microstruture within austenite grain boundaries for the 13-8 Mo Supertough®;, and a martensitic matrix within austenite grain boundaries with small round carbides for the modified M50. Further metallurgical investigations include Charpy Impact testing, SEM analysis, and EDS to determine the carbides in the microstructures. All data will be compiled to compare to the K12®; dual phase armor plate to see if the designed bimetallic armor would be a suitable replacement.

 

 

 


 

 

Student Author(s): 

Denney, Jason L.

Department(s):

Electrical Engineering

Research Mentor(s)

Michael J. Escuti/Electrical Engineering

Title of Presentation:

Optimizing Liquid Crystal Display Fabrication

 

 

The focus of this research project is to improve the fabrication of a unique diffraction grating called the liquid crystal polarization grating (LCPG), a novel and an increasingly important electro-optical element. The central problem to be solved is that unwanted optical scattering results whenever the functional polymer known as a photo-alignment layer does not properly align the liquid crystal after the ultraviolet holographic exposure. This leads to decreased diffraction efficiency, and most importantly, limits the smallest grating period for high diffraction to just under nine micrometers (five microns or less is desired). Our primary approach to solve this problem is to systematically vary the exposure time and measure the light scattering vs. angle with the automated dynamic light scattering measurement system I have built from scratch in the previous summer. We are in the process of fabricating many comparable samples with only one fabrication parameter different, in order to find the narrow window within which the energy dose enables the photo-alignment layer to have the maximum anchoring energy. An additional set of measurements will be performed to characterize key electro-optical properties on the light diffracted and create a library of data for various materials that will be a significant contribution suitable for publication.

 

 


 

 

 

Student Author(s): 

Dupor, Stevan M.

Department(s):

Electrical and Computer Engineering

Research Mentor(s)

Subhashish Bhattacharya/Electrical and Computer Engineering

Title of Presentation:

Ethernet/IP Implementation at the Network and Application Layer for a Power Electronics System

 

 

The single chip Ethernet/IP solution using the Freescale MC9S12NE64 16-bit microcontroller is a critical component of a larger generic control system being developed at the Semiconductor Power Electronics Center (SPEC) for power electronic applications. Current systems for controlling large inverters and/or converters in power electronics are very specific to the application being addressed. Although real-time control has been obtained for particular problems, the control hardware and its underlying software do not adapt well to a system change. The prevalent method of providing user interface through a PC parallel or COM port imposes certain system constraints. The Ethernet/IP solution being developed by us would enable universal connectivity of any power electronics system. Research work is primarily on the TCP/IP stack implementation and the application layers for Ethernet/IP. An existing TCP/IP freeware source code is taken as the base and modified to suit our system requirements. These system level changes in the base code are done to enable communication with the real-time control processor that does computations for power control. Labview is the application layer software used for this project. Virtual instruments (VIs) for Labview are being written as a part of this project to enable TCP/IP communication with our system. From the power electronics point of view, having a generic control system that could have a user interface through a widely used application such as Labview, would be invaluable. On a broader level, this research draws upon knowledge from embedded systems to provide an elegant solution to a practical problem faced in power electronics. Although the system control actions are initiated on a real-time control board using high speed digital signal processors (DSPs) and field programmable gate arrays (FPGAs), user interface is provided using the framework of Ethernet/IP communication with the Labview front panel.

 

 


 

 

 

Student Author(s): 

Field, Ryan M.

Department(s):

Electrical Engineering

Research Mentor(s)

Maysam Ghovanloo/Electrical Engineering

Title of Presentation:

Particle Swarm Optimization for Tracking a Magnetic Dipole with Five Degrees of Freedom

 

 

The purpose of this project is to extend the technology utilized in the Tongue Drive system developed at the NC-Bionics lab to improve its capabilities for environment control and also create new applications in the field of “articulography”. Current state-of-the-art devices require hardwired transmitter coils to be attached to the tongue and tracked via external receivers. These coils impose constraints on the ability of a patient to accurately reproduce normal speech due to the wires that must pass into the mouth through the lips. We intend to replace the powered transmitters with permanent magnets, which are inherently wireless and would allow the patient to be more comfortable and better able to reproduce their true speech. There are two major challenges associated with this technology: developing a magnetic sensor array system capable of detecting small changes in magnetic fields and then computing the location and orientation of one or more magnets, attached to the tongue, based on the recorded sensor array information. There are commercially available and sensitive Hall-effect magnetic sensors that partially solve the first problem. However, it is still necessary to determine where the sensors should be placed. Another problem is computing the exact location of the magnetic dipole relative to the sensor array. Previous research has found that there need to be at least three sensors to cancel the earth’s magnetic field and an additional five sensors to provide sufficient information to solve for the five degrees of freedom of the dipole (x, y, z, θ, φ). My research is concerned with implementing an algorithm to solve for these unknowns and I have recently implemented an algorithm that utilizes Particle Swarm Optimization (PSO) to find the global minimum of an arbitrarily complex function.

 

 


 

 

 

Student Author(s): 

Fox, Paul

Gotchy, Justin

Thorton, Jackson

Department(s):

Materials Science and Engineering

Research Mentor(s)

C.M. Balik/Materials Science and Engineering

Title of Presentation:

Increasing the Radiation Resistance of Cold Applied Gel Sealing Technology

 

 

 

This research examines cold applied gel sealing technology for the insulation of electrical components in nuclear power plants. The current PowerGel® used as a gel sealant by Tyco Electronics is problematic as it undergoes crosslinking under large doses of irradiation, becoming very viscous and losing its sealing properties. The purpose of this research is to find a suitable replacement for this polydimethylsiloxane (PDMS)-based PowerGel®. Based on the results of previous research, the addition of phenyl groups is known to provide radiation stability. Five samples of phenylated siloxane fluids, ranging in phenyl content from 5% - 50%, have been irradiated at six different doses in 25 kGy increments from 25 kGy –150 kGy. Measurement of viscosity change as a function of dose is used to analyze the radiation resistance of the gels. The miscibility of these fluids with a high molecular weight vinyl terminated PDMS has also been tested to determine the feasibility of creating a gel similar to the PowerGel®. It was found that only gels with 5% phenyl content are miscible in the vinyl terminated PDMS, and this is the only fluid that can be synthesized into a gel without altering the chemistry. A gel using this fluid was synthesized which displayed similar properties to the PowerGel®. Both gels were irradiated at 150 kGy and analyzed. The results of this analysis will be presented and discussed.

 

 


 

 

 

Student Author(s): 

Furst, Stephen, J.

Brown, J. Adam M.

Freeman, Carolyn M.

Blankenship, Taylor M.

Department(s):

Mechanical and Aerospace Engineering

Research Mentor(s)

Andre Mazzoleni/Mechanical and Aerospace Engineering

Title of Presentation:

Lunar Hard-Lander Design, Fabrication, and Drop Testing

 

 

The lunar hard-lander concept is being developed as a means of robotically surveying the Moon or other solar system bodies. The hard-lander is capable of limiting payload acceleration to 1000 G’s during a 60 m/s impact. The ability to impact at this speed makes a complex retromotor and guidance system unnecessary. Our hard-lander design uses a thick layer of aluminum honeycomb to protect an instrument payload stowed inside. Aluminum honeycomb has a constant crush strength and an extremely high crush strain, so during an impact it provides the payload with an essentially uniform deceleration. As a result, there are no destructive peaks of acceleration. Also, our design is spherical and, as a result, it can survive an impact at any orientation. The payload is further housed in a rigid, carbon fiber shell. A telescoping shaft extends out from the payload housing to provide a corridor for the payload to escape through, even after the impact deforms the energy absorber. Payload ejection will allow certain instruments and spacecraft components to be in direct contact with the lunar regolith. The entire diameter of the entire hard-lander is less than 1.2 m and has a mass of about 30 kg. The payload module is designed so that it will self-stabilize into a predetermined orientation after being ejected via airbag from the energy absorbing material. To prove this concept, we have created twelve test coupons and fired them from a compressed air cannon to verify the dynamic crush strength of the aluminum honeycomb. Also, we have built and tested mock-ups of the self-stabilizing payload and airbag ejection system. Finally, we have created two prototypes in which we will mount an accelerometer. In the coming weeks we will drop test our prototypes from 500 ft to verify the crush model for a spherical energy absorber.

 

 

 


 

 

Student Author(s): 

Going, Ryan W.

Department(s):

Electrical Engineering

Research Mentor(s)

Michael J. Escuti/Electrical Engineering

Title of Presentation:

Hydro-Dynamic Studies of Ellipsoidal Particles in a Non-Uniform Optical Field

 

Non-contact manipulation of dielectric particles with optically-induced forces and torques is an important goal of optical-trapping, and has tremendous value in the fields of biomedical engineering (e.g. cell cytometry) and nanotechnology (e.g. nanoparticle filtering). It is well known that analytic expressions can be found for the force and torque on a spherical particle in an arbitrary electromagnetic field (even in many textbooks on electrostatics). However the geometry of an ellipsoidal particle in a non-uniform field presents unique problems, such that closed expressions for these two quantities (i.e. force and torque) have yet to be seen in the cur-rent literature. Approximations which can be made when the field is uniform or the particle spherical cannot be made in this case, thus the most rigorous approach is to use the Maxwell Stress Tensor method. This method requires knowledge of the electric field just on the boundary of the particle. The electric field was solved using ellipsoidal harmonics, which are known solu-tions to the Laplace equation in ellipsoidal coordinates, and a taylor expansion of the applied electric field about the center of the particle in ellipsoidal coordinates. Various multipole terms have been produced by this method. The current research being done involves using these ex-pressions in the Maxwell Stress Tensor to derive the force and torque for an arbitrary spheroid in an arbitrary field. The applications of these expressions are numerous, but especially useful in biological sciences, as dielectric spheroids can accurately approximate many cell structures and their electrical properties.

 

 


 

 

Student Author(s): 

Gould, Troy D. 

Department(s):

Chemical and Biomolecular Engineering

Research Mentor(s)

George W. Roberts/Chemical and Biomolecular Engineering

Nathaniel A. Cain/Chemical and Biomolecular Engineering

Title of Presentation:

Measurement and Modeling of Polystyrene Viscosity in Supercritical CO2 Expanded Decahydronapthalene

 

 

Polystyrene is one of the four most-used commercial plastics in the US. One use of this polymer is to produce hydrogenated polystyrene, which offers enhanced thermal and chemical properties. Typically heterogeneous catalytic hydrogenation of polystyrene has slow reaction rates associated with slow mass transfer rates, but offers high yield and purity of the end product. Supercritical fluids offer enhanced diffusivity and lower viscosity which can increase these slower mass transfer rates. This research will focus on the heterogeneous catalytic hydrogenation of polystyrene in supercritical CO2 expanded decahydronapthalene (DHN). In order to learn more about this solvent system, and the effects it will have on the polystyrene, viscosity and phase behavior studies have been conducted. A high-pressure phase behavior apparatus was used to measure bubble points of the DHN and supercritical CO2 solvent system. Binary interaction parameters were calculated from this data to model the system with the Sanchez-Lacombe equation of state. The mixture parameters obtained from the phase behavior data were applied to a free-volume viscosity model for the DHN and DHN/CO2 solvents. This model was compared to experimental viscosity data taken at varying compositions, temperatures, and pressures. The novel application of the free-volume viscosity model fits the data surprisingly well. The next stage in this research is to obtain viscosity data on the single fluid phase solution of polystyrene in DHN/supercritical CO2. After viscosity data is obtained, the next stage will be to carry out the hydrogenation of polystyrene in an integral recycle reactor. This will allow the evaluation of various catalysts and to accurately study the kinetics of the reaction for later use in a continuous reactor.

 

 

 


 

 

Student Author(s): 

Hodges, Ryan D. 

Schimizzi, Ryan D.

Department(s):

Electrical and Computer Engineering

Research Mentor(s)

Michael B. Steer/Electrical Engineering

Title of Presentation:

Anechoic Chamber for Combined Electromagnetic and Acoustic Tests

 

 

All objects have acoustic and electromagnetic characteristics determined by their physical attributes, material make-up, and physical orientation relative to the source. Traditionally these characteristics would be determined separately. However, due to the difference in the speeds of light and sound, acoustic waves in the range of 20Hz to 20 kHz have the same wavelength as electromagnetic waves in the range of 17.5 MHz to 17.5 GHz respectively. This phenomenon makes the existence of a combined acoustic and electromagnetic chamber a useful analysis tool. The concept is that the interaction of electromagnetic and acoustic signals can be used to characterize objects. The materials used in the construction of the chamber as well as the physical dimensions of the chamber all contribute to the final characteristics. To achieve the desired isolation from outside noise sources and minimal internal reflection, several layers of acoustic and electromagnetic radiation absorption materials were used. The innermost layer consists of pyramidal foam tiles designed specifically for the internal reflection and absorption of electromagnetic energy. The next layer is a tile comprised of polypropylene beads followed by a tile of melamine foam. The outer layer consists of heavy polymer material matting. The entire chamber is encased by copper mesh to form a faraday cage which blocks electromagnetic fields from entering or exiting the chamber. Preliminary tests have shown that the chamber reduces ambient acoustic noise relative to the open but quiet lab environment. Isolation from outside noise sources is approximately 60 dB.

 

 


 

 

Student Author(s): 

Hon, Emily W.

Department(s):

Chemical and Biomolecular Engineering

Research Mentor(s)

Bridgette Budhlall/Chemical and Biomolecular Engineering

Orlin D. Velev/Chemical and Biomolecular Engineering

Title of Presentation:

Light Response of poly-N-isopropylacrylamide Hydrogels Containing Gold Nanoparticles

 

 

Hydrogels are water-insoluble, crosslinked polymer chains that are dispersed in water. They are important in many applications, some of which include cosmetics, coatings, and foods. Particularly important is the potential role of hydrogels in drug delivery. Hydrogels could prove to be an effective way to transfer antibiotics or other drugs to different locations in the body because of their sensitivity to pH, temperature, and light. However, in previous studies, the reaction time of the hydrogel has been slow. In this experiment, we investigate poly-N-isopropylacrylamide-based hydrogels with and without the addition of gold nanoparticles and their responses to light. Poly-N-isopropylacrylamide (pNIPAM) microcapsules were prepared via photopolymerization. The pNIPAM microcapsules respond to light and heat by expelling water and shrinking, while swelling with water when not exposed to light and heat. Because gold is a metal conductor, it is believed that the dispersed nanoparticles will be able to focus light and heat, causing a faster response. The goal of this project is to develop a swelling and deswelling ratio between pNIPAM with gold and without gold over several exposures to high and low light. Data will provide a quantitative correlation of the effectiveness of gold nanoparticles.

 

 

 


 

 

Student Author(s): 

 Hume, Samuel

Department(s):

 Electrical and Computer Engineering

Research Mentor(s)

 Winser Alexander/Electrical and Computer Engineering

Title of Presentation:

 A Comparison of Tools Used to Analyze System Characteristics of Biochemical Models

 

 

The project involved an evaluation of two simulation packages along with the use of the Systems Biology Markup Language (SBML) to describe and analyze biological systems. Identifying a unified way to describe and analyze biological systems in software is a critical component of systems biology research. It is a necessity to have information standards if models are to be shared, evaluated, and cooperatively developed. Otherwise, a considerable amount of time would be spent translating biochemical reactions models from one representation to another, and valuable information could be lost in the process. The Systems Biology Markup Language (SBML) is a free and well-accepted XML-based language for representing and exchanging models between simulation and analysis tools. The SBToolBox for MATLAB and the Systems Biology Workbench (SBW) were the simulation packages used in the evaluation. The metrics used for performing the comparative analysis of the above tools were: steady-state analysis and stability analysis, timed simulation analysis, in-silico experiments, bifurcation analysis, parameter estimation, and parameter sensitivity. The goal for the project was to provide information for use to decide which tool is better suited for the analysis of a given model.

 

 

 


 

 

 

Student Author(s): 

Hwang, Christopher J.

Department(s):

Duke Clinical Research Institute, Duke Electrical Engineering

Research Mentor(s)

Richard Becker/Duke School of Medicine

Title of Presentation:

Investigation in Coherent Anti-Stokes Raman Scattering (CARS) Microscopy/spectroscopy as a Non-invasive Method for Detection of Thrombotic Events

 

 

The imaging and study of live complex biological systems has always been of great interest. However, problems with obtaining high-resolution images without invasive procedures has proven difficult. Infrared radiation tuned to characteristic vibration frequencies of chemical species has yielded great chemical selectivity, however the longer wavelength of infrared light has limited its spatial resolution. Fluorescent dyes or tags have improved spatial resolution, however this requires long preparation times and risks altering chemical or molecular behavior. Raman spectroscopy tuned to molecular vibrations has given great chemical selectivity without staining, but requires long scan times due to the weak Raman signal. Applications of coherent anti-Stokes Raman scattering (CARS) microscopy has allowed for high-speed, high spatial resolution, three-dimensional imaging without the use of fluorescent dyes or tags. Currently CARS microscopy shows great strength in lipid detection. Research was conducted at the Duke Clinical Research Institute and Electrical Engineering department investigating the possibility of using CARS microscopy/spectroscopy as a non-invasive method for detecting or monitoring coagulation or thombotic events. Research included studying current literature and personal interviews with leaders in the CARS microscopy field along with preliminary experiments on a lab-grade Raman spectrometer at the DUKE ECE department. Bovine Serum Albumin along with clotting proteins fibrinogen and thrombin were tested for detection by Raman spectroscopy. Results from testing showed albumin concentrations as low as the millimolar range can be detected by the lab-grade spectrometer, however no significant signal was obtained from the clotting proteins. CARS microscopy has strengths in detecting lipids, where much of the current research is focused. Thus, the possibility for shifting focus to lipids specific to clotting events exists in future research.

 

 


 

 

 

Student Author(s): 

Jackson, Lauren C.

Department(s):

Materials Science and Engineering

Research Mentor(s)

Richard Knight/Materials Science and Engineering, Drexel University

Richard Cairncross/Materials Science and Engineering, Drexel University

Milan Ivosevic/Resodyn Corp.

Title of Presentation:

Sliding Wear Properties of HVOF Thermally Sprayed Nylon-11 and Nylon-11/Ceramic Composites on Steel

 

 

The high velocity oxy-fuel (HVOF) combustion spray process has previously been shown to be a successful method for depositing pure polymer and polymer/ceramic composite coatings. Polymer and polymer-ceramic composite particles have high melt viscosities and require the high kinetic energy of HVOF in order to generate sufficient particle flow and deformation on impact. One of the goals of reinforcing polymer coatings with particulate ceramics is to improve their durability and wear performance. Composite coatings were produced by ball-milling 60 μm Nylon-11 together with nominal 10 vol.% of nano and multi-scale ceramic reinforcements and HVOF spraying these composite feedstocks onto steel substrates to produce semi-crystalline micron and nano-scale reinforced coatings of polymer matrix composites. The room temperature dry sliding wear performance of pure Nylon-11, Nylon-11 reinforced with 7 nm silica, and multi-scale Nylon-11/silica composite coatings incorporating 7 to 40 nm and 10 μm ceramic particles was determined and compared. Coatings were sprayed onto steel substrates, and their sliding wear performance determined using a pin-on-disk tribometer. Coefficient of friction was recorded and wear rate determined as a function of applied load and coating composition. Surface profilometry and scanning electron microscopy were used to characterize and analyze the coatings and wear scars.

 

 


 

 

Student Author(s): 

Joshi, Shaunak

Department(s):

Electrical and Computer Engineering

Research Mentor(s)

Yan Solihin/Electrical and Computer Engineering

Title of Presentation:

Analytical Cache Performance Prediction

 

 

Cache memory continues to play an increasing role in the overall performance of microprocessor systems as the difference between processor and memory speed increases. It is well known that except for the cache size, there are several other factors that affect cache performance such as associativity, replacement policy etc. As a result, a high level performance model will be very helpful in narrowing cache design space and gaining insights as to how each factor affects cache performance. Dr. Yan Solihin and his group have developed algorithms that provide these high level performance models. My research involves creating a tool suite, called ACAPP, which integrates the algorithms developed by Dr. Solihin’s group. ACAPP is integrated into SimpleScalar, the standard simulator used by the computer architecture and performance modeling communities. This tool allows the algorithms to be widely disseminated through the abovementioned communities. The input of ACAPP is the Circular Sequence Profile which can be obtained through simulation. The output of ACAPP is the predicted cache miss rate for different replacement policies and different associativities for a single application. The tool suite can also predict the miss rates of two applications that share the same level of cache (typically L2). I modified the SimpleScalar simulator to support the functionality of generating circular sequence profiles for inputs. I also implemented a user-interface to allow the user to easily obtain prediction results. Moreover, I added the functionality of predicting performance for caches with user-defined replacement policies into the tool suite. ACAPP was introduced on February 2007 at a tutorial at the 13th Symposium for High-Performance Computer Architecture in Phoenix, Arizona and has been released to the public. So far, the tool suite has generated a lot of interest with researchers at University of Texas at Austin, University of Wisconsin and Kyushu University in Japan.

 

 


 

 

Student Author(s): 

Karra, Kiran

Department(s):

Electrical and Computer Engineering

Research Mentor(s)

Brian L. Hughes/Electrical and Computer Engineering

Title of Presentation:

Numerical Analysis of Spatial Correlation in Diversity Receivers with Coupled Antennas

 

 

The primary impairment for wireless communications is fading - the random power fluctuations that result from constructive and destructive interference of scattered radio waves. Many techniques can be used to overcome fading, which include diversity transmission and reception, space-time codes, and MIMO. This presentation will focus on diversity reception, which entails using multiple antennas to receive signals. Diversity receivers work on the principle that if the antennas are placed far enough apart, one of them may receive a stronger signal than the other. However, in mobile communications equipment such as cell phone, space is very limited. As a consequence, the signals that are captured by the antennas electromagnetically couple. This means that the signals are correlated, which leads to reduced performance. Under certain assumptions, in a narrowband fading channel, the fading may be modeled statistically as the correlation of electromagnetic waves in free space at two separate points, which is given by a zeroth order Bessel function. This holds true for the correlation of open circuit voltages between two uncoupled antennas. However, if two antennas are coupled, then current in one antenna can induce current in the other antenna. The mutual coupling between antennas may be solved analytically for the case of two infinitesimally thin dipoles. We wish to explore the effect of mutual coupling on diversity performance for more realistic cases. To do so, we use a numerical electromagnetic software package to determine the open circuit correlation between an array of dipole antennas of finite thickness. To relate these numerical results to the established theory for uncoupled antennas, we fit the data to a series of Bessel functions of increasing order. Our NEC simulations have shown that adding Bessel functions of higher orders proportionally will allow us to predict signal correlation of coupled antennas.

 


 

Student Author(s): 

Katz, Donald

Department(s):

Civil Engineering

Research Mentor(s)

John R. Stone/Civil Engineering

Title of Presentation:

Development of Typical Truck Trip Profiles for Rural and Urban NC

 

Efficient freight transportation is critical to a healthy economy for North Carolina (NC). Trucking, in particular, provides a vital and reliable mode of transporting regional and intra-regional goods movements in NC.  On the other hand, the fast growth in truck flows has significantly contributed to traffic congestion, vehicle emissions, and pavement and bridge damage. Since the effect of truck loads on pavement and bridge performance increases exponentially with truck weight, it is important to quantify the cost of heavy truck and overweight trucks to the NC roads system as a whole. Accurate information on truck weight distributions can assist DOT transportation planners and engineers to estimate the cost of early failure of the NC road system due to heavy and overweight trucks, and accordingly determine equitable fee structures and weight law enforcement. Using overweight truck data from NCDOT, a profile of Interstate 40 was created. Its distribution of truck weights and frequency for each mile marker shows where the most critical portions of the highway are. Although this only reflects one week of data, the profle will help motivate NCDOT to provide additional data in the future. With a years worth of data, a complete profile can then be created. This will show where the focus areas are on this one particular highway. The process of creating this profile shows problems which will need attention when streamlining the profile creation process. Roads which interset the highway multiple times, roads with multiple names, and decision rules to work by were all encountered. It is necessary to provide thorough instructions if this were process were to be continued manually, or if it were programmed for a computer to work through.

 

 

 


 

 

 

Student Author(s): 

King, Matthew R.

Disseler, Steven M.

Department(s):

Materials Science and Engineering

Research Mentor(s)

Jerry Cuomo/Materials Science and Engineering

Title of Presentation:

Atmospheric Plasma-Enhanced Soft Hydrolysis of Southern Pine

 

 

The production of fermentable sugars from southern pine using atmospheric plasma (AP) was studied. AP processing in the dielectric barrier discharge (DBD) configuration was coupled with acid hydrolysis in an effort to determine how AP can impact a standard conversion technique. The effects of plasma chemistry (5%O2/95%He and 5%Air/95%O2), treatment time (10 seconds and 10 minutes), and electrode polarity (top-driven and bottom-driven) on the production of sugars were evaluated using HPLC, FTIR, and SEM. It was found that AP-treated samples produced over 50% more total sugar than untreated samples. It was also found that the AP process degrades the lignin component of the substrate, a significant inhibitor to sugar production. Treatment time was the most significant factor in sugar production, although plasma chemistry had an effect on the surface chemistry of the substrate. With such an increase in sugar production for treated samples, this process has the potential to significantly impact the efficiency and cost-effectiveness of the biomass conversion process.

 

 


 

 

 

Student Author(s): 

Kirkpatrick, Casey J.

Department(s):

Electrical and Computer Engineering

Research Mentor(s)

Mehmet C. Ozturk/Electrical and Computer Engineering

Title of Presentation:

Hall Effect System for Semiconductor Measurements

 

When a DC current flows through a semiconductor in the presence of an orthogonal magnetic field, a voltage can be measured perpendicular to the direction of the applied current. This phenomenon is referred to as the Hall Effect and it is commonly used to measure the mobility and active carrier concentration in thin crystalline layers grown on semiconductor wafers. The project started in spring 2007. The initial work involved acquiring the components to set up the Hall Effect measurement system, which included a light-tight sample box with internal probes, a DC electromagnet, a gauss meter, and an electronic controller, which serves as a precision current source and voltmeter. The sample holder was designed as part of this work and it was manufactured by the NCSU precision machine shop. After the system set-up was complete, the preliminary work focused on optimizing the measurement parameters for reliable measurements. The effects of the measurement current and the magnetic field were investigated. It was found that that the measurement current had an optimum range to achieve a high signal-to-noise ratio and avoid sample heating. It was found that once sufficiently high, the magnetic field had no observable effect on the measured properties. The long-term objective of this work is to carry out fundamental studies on heavily boron doped, p-type Si-Ge alloys grown on n-type Si wafers by ultrahigh vacuum rapid thermal chemical vapor deposition. Preliminary results indicated that the system is capable of producing reliable measurements. The current phase of this work is focused on the impact of strain on the mobility and active carrier concentration in heavily boron doped SiGe layers. The amount of strain in the epitaxial layer is adjusted by growing the films at different thicknesses to achieve films that are strained and fully relaxed.

 

 

 

 


 

 

 

Student Author(s): 

Lawler Jr., Kristopher F.

Department(s):

Electrical Engineering

Research Mentor(s)

John F. Muth/Electrical Engineering

Title of Presentation:

Design of a MEMs Torsional Mirrors

 

 

The mask design of an array of MEMs Torsional Mirrors is presented. The design allows the mirrors to be individually electrically addressed. By incorporating these mirrors as part of a Fabry Perot cavity, the frequency of mechanical vibration of the mirrors can be monitored and displacements measured with very high precision. One application of these mirrors is chemical and biological sensing.

 

 


 

 

 

Student Author(s): 

Marshall, Kristina

Felker, Angela

Rebovich, Mary

Department(s):

Materials Science and Engineering

Research Mentor(s)

Rich Spontak/Materials Science and Engineering

Title of Presentation:

Development of Bonding and Matching Layers for Acousto-Optic Device Applications

 

 

The purpose of this senior design project was to identify and design an acoustic impedance matching layer and a bonding layer for an acousto-optic (AO) device to expand Northrop Grumman’s knowledge base concerning these layers and aid in the development of a more efficient AO device operational in the infrared light range. The team studied the chemical compositions and bond strengths of three Norland Optical Adhesives (NOA):61, 68 and 81. Analysis through Fourier Transform Infrared (FTIR) spectroscopy of these bonding materials illustrated the various compositions and chemical bonds present. Qualitative comparison of the adhesives through peel tests provided information about relative bond strengths. The team explored the possibility of combining the matching and bonding layers by incorporating typical matching layer nanoparticles into the adhesives, and these combinations were analyzed via measurement of the dielectric loss constant and peel testing.

 

 


 

 

 

Student Author(s): 

Morrow, Joseph M.

Department(s):

Mechanical and Aerospace Engineering

Research Mentor(s)

Ashok Gopalarathnam/Mechanical and Aerospace Engineering

Jeffery Jepson/Mechanical and Aerospace Engineering

Title of Presentation:

Increasing Fuel Economy in Aircraft by Decreasing Drag

 

 

In order to study the drag properties of airfoils, significant attention has been directed towards two-dimensional computational studies and experimental testing. To simulate two-dimensional flow, special focus has been given to wind tunnel models spanning the entire test section. By extending the wingtips until flush against the sidewalls of the wind tunnel, finite wing effects on flow variation can be greatly reduced, allowing for the two-dimensional cross-section to be studied. Two-dimensional cross-sectional studies are believed to uncover clues leading to decreasing drag and increasing fuel consumption. This poster presents a possible method for correcting inaccurate pressure data due to natural flow variation and outlines a method for drag coefficient calculation of two-dimensional airfoils using wake pressure scans of a multi-flapped, multi-sectioned, auto-adaptive 2-D airfoil. Initial results indicate that integrating wake scans can provide acceptable figures for accurate drag coefficient calculation, but further testing must be carried out before this can be confirmed. The multi-flapped airfoil used in these experiments features automatic adaptive capabilities. The algorithm used in this process ensures that the airfoil maintains low drag while providing necessary lift. This poster proposes a method to calculate the drag properties of the adaptive airfoil and confirm its ability to minimize drag under low-speed conditions. Upon verification of drag reduction, the implementation of the adaptive airfoil may increase fuel economy by decreasing drag.

 

 


 

 

 

Student Author(s): 

Mulholland, Gregory J.

Department(s):

Electrical and Computer Engineering

Research Mentor(s)

Veena Misra/Electrical and Computer Engineering

Title of Presentation:

Comparative Investigation of Redox-active Molecular Band Interactions with Semiconductor Substrates

 

 

Molecular electronics are a hotly debated emerging field with great potential for advancing bottom-up nanoscience approaches to building gigascale-density computing devices. Specific synthetic organic molecules have shown requisite electrical properties for charge and spin devices; but the energy state interactions are not well understood. The investigation of the band-chemical potential interactions in molecular layers is important to understanding detailed mechanisms for metal contacts with these molecules. In recent work, it has been shown that the substrate type matters greatly to the performance of the device. On p-type silicon, molecular capacitors behave as expected under dark standard laboratory conditions. Standard capacitive charging current is seen, with a peak in current at the specific oxidation-reduction (redox) potentials of the molecules. Only under the application of light do n-type devices begin to show the characteristics of p-type devices. This suggests that by optical generation of holes in the valence band in n-type Si, the conditions for charge transfer are improved. The chemical potential of the molecular layer aligns itself with the Fermi level of the semiconductor, but actually exchanges electrons with the valence band. The Highest Occupied Molecular Orbital of the organic layer is comparable to the valence band of the semiconductor, while the Lowest Unoccupied Molecular Orbital is comparable to the conduction band. When a bias is applied, an electron tunnels from the organic layer to the semiconductor valence band. To accurately gauge the correct band structure of these devices, substrates of varying band offsets must be chosen. Fc-BzOH molecules were attached to n-type Silicon (Si) and Germanium (Ge) substrates and tested for light dependence, scan rate dependence, and oxidation-reduction voltages using Cyclic Voltammetry. Preliminary Ge samples show redox at higher voltages than that of n-type silicon, corresponding to the band offset of the Ge valence band relative to Si.

 

 

 


 

 

 

Student Author(s): 

Munilla, Samuel R.

Jhala, Arnay

Rawls, Curtis

Macik, Amanda

Department(s):

Computer Science

Research Mentor(s)

R. Michael Young/Computer Science

Title of Presentation:

Longboard, Toward an Intelligent Storyboarding Tool

 

 

Longboard is a collection of tools used for generating movies on game engines. Users can author scripts and visualize them on the Unreal Tournament game engine. Longboard provides an intuitive Tablet PC interface for authoring scenarios and sketching storyboard frames that are communicated to a game engine controller for execution. Longboard communicates with an external planner – Darshak – for planning intermediate unspecified actions from the user generated scenario. In the Longboard system, users specify movie directives through a storyboarding interface. The Tablet PC provides a natural interface for drawing storyboard frames. Users have the freedom to sketch characters and objects through the pen using the built-in drawing functionality. This avoids having the user learn manipulation of 3D models in the interface. Pen input provides a shallow learning curve for users, interpreting both stick-figures and professionally drawn characters. The stroke recognition system also allows users to annotate the storyboard frames with text and stage directions in addition to characters and objects in the 3D world. The story and camera planners allow a user to create a partial specification for an action sequence of the movie and then add remaining actions to automatically complete full scenes. Users create a script and a set of storyboards in the Longboard user interface. The advantage of having a planner in the system is that users may not want to specify every action or camera placement in their film. Users can either accept or reject the suggested shots by the planner by specifically adding constraints on certain frames or by adding new frames to the storyboard. The user can then send the completed plan to the Renderer. The Renderer takes advantage of game engine technology to create a video of a rich 3D environment. The Longboard Renderer uses the Unreal Tournament engine to create a virtual world that has a library of sets for setting up the film environment. The Renderer's Execution Manager manipulates the actors and camera to follow the action sequence specified by the Longboard interface.

 


 

 

 

Student Author(s): 

Nobles, Larrisha R.

Department(s):

Chemical and Biomolecular Engineering

Research Mentor(s)

Richard J. Spontak/Chemical and Biomolecular Engineering, Material Science and Engineering

Title of Presentation:

Surface Modification of Electrospun Polymer Blends

 

 

Currently, there are few single-step methods designed to functionalize the surface of polymer nanofibers. Therefore, this project explores the feasibility of achieving single-step surface modification via electrospinning. Through this unique process, fibers ranging from tens of nanometers to tens of microns in diameter can be produced by using an electric field to overcome the surface tension of a polymer solution or melt. The ultrathin fibers produced by electrospinning are suited for a diverse range of applications due to their large surface area to volume ratio. The objective of the present research is to fabricate surface-biofunctionalized nanofibers composed of several different polymers (e.g., polymethyl methacrylate, PMMA) via addition of novel bio-organic co-oligopeptides composed of SEE and RGD domains. The effects of added co-oligopeptide on fiber morphology and surface chemistry are deduced by scanning electron microscopy and x-ray photoelectron spectroscopy, respectively. Current objectives of this research project include studying the elctrospinning of PMMA and PMMA/PEO blends for their use as the fiber-forming polymer. In addition to surface modification, the effect of selective PEO extraction of PMMA/PEO blends on fiber morphology has been investigated.

 

 


 

 

Student Author(s): 

Poovey, Jason

Department(s):

Electrical and Computer Engineering

Research Mentor(s)

Thomas M. Conte/Electrical and Computer Engineering

Title of Presentation:

Benchmark Characterization of the EEMBC Benchmarks

 

 

Benchmarking has long been used to measure the performance of desktop systems, servers, and high end computers. In these situations, the characteristic architecture and applications that are run are well known in advance. In the market of embedded processors; however, the workloads vary greatly. Because of this, it is very difficult to create a suite of benchmarks that accurately depicts any given user’s workload. Instead, the best option is to create a suite of lightweight benchmarks with varying workloads. One such benchmark suite, and the test suite of this research, is the EEMBC Suite of Benchmarks which is an industrial consortium that creates these industry-standard benchmarks for embedded microprocessors. This research aims to fully characterize each of the EEMBC benchmarks, examine the benchmark’s effectiveness and give developer’s data with which to compare workloads to the characterization. The purpose of characterization is to give a common set of metrics for all benchmarks and classify them based on their performance in each metric. Some example metrics are IPC, Cache Size, and Branch Misprediction. Bringing the data of each metric together in a single graph reveals a”shape” for each benchmark. From this shape we are able to see characteristics such as which benchmark is “memory active” or hard to predict. This data is analyzed to determine the overall effectiveness of the EEMBC benchmarks, and it allows users to match their workloads to a specific EEMBC benchmark, thus allowing them to build a design that is optimal for that characterization. The final goal is two-fold. Data is being collected to fully characterize the benchmarks in all of the EEMBC suites, and is almost complete. We are beginning to transition into the next phase which is to automate the tools used for characterization so that users can characterize their own code.

 

 


 

 

Student Author(s): 

Ravichander, Aparna

Bowman, Michelle

Department(s):

Chemical & Biomolecular Engineering

Materials Science & Engineering

Textiles & Polymer Science

Research Mentor(s)

Richard J. Spontak/Chemical Engineering, Materials Science

Tushar Ghosh/Textiles and Polymer Science

Title of Presentation:

Electrical and Mechanical Properties of Carbon Nanofiber and Carbon Nanotube Block Copolymer Composites

 

 

Carbon nanoparticles have been used as excellent avenues to convert insulating polymeric materials to electronically conducting materials. When a polymer containing carbon nanoparticles is exposed to a particular strain, the nanoparticles shift and touch one another, forming a connecting channel for an electric current to pass through. This percolation threshold allows for a material to behave as a conductor, as a deformation is applied, and an insulator, when the material is relaxed. In this work, 0.5 wt% carbon nanofibers (CNF) and 0.5 wt% carbon nanotubes (CNT) have been added to a polystyrene-b-(ethylene-co-propylene)-b-styrene (SEPS) triblock copolymer block copolymer. The composites were both solvent cast, yielding isotropic materials, and extruded, resulting in anisotropic nanocomposities. Since fibers have a much higher aspect ratio than spherical particles, a lower concentration of nanoadditives is required to reach the percolation threshold of these SEPS/carbon fiber nanocomposites. The isotropic and anisotropics samples yield markedly different resistivity data. Also examined were thermoplastic elastomer gels consisting of 10 wt% SEPS and 90% mineral oil. Since these materials are highly elastic, they require more strain to reach the percolation threshold, and given a broader curve for the log R (resistivity) vs. l/lo (deformation) data. According to the data, the percolation threshold was not achieved implying that the SEPS/oil materials require a higher concentration of CNFs and CNTs to reach the percolation threshold.

 

 

 


 

 

 

Student Author(s): 

Ross, Matthew E.

Goodwin, William

Lazar, Kevin

Department(s):

Materials Science and Engineering

Research Mentor(s)

Michael Rigsbee/Materials Science and Engineering

Title of Presentation:

Failure Analysis of Crane Wire Rope

 

 

The research has focused on determining the cause for premature fracture in operating crane cable wire ropes at Nucor Steel - Hertford. Wire rope is used extensively in crane and elevator operation, as well as, in suspension bridges, roller coasters, and moorings. A typical wire rope consists of many strands of steel wires. These strands are then woven together in a variety of ways to create a high strength wire rope. Most wires are assembled from high-carbon, plain carbon steel which are heavily drawn with extremely cold-worked microstructures. Individual wires within the cables are subjected to varying stresses including tension, compression, torsion, and shear. This is due to wires sliding and bending over one another which ultimately results in a system that can attain very high strengths while retaining flexibility. Failure analysis was performed to determine the fracture mechanism and a proposal was formulated to optimize operation parameters and on the specific type of wire rope used. It was determined that abrasions to the outer wires combined with the torsional nature of the stresses within the wire rope caused longitudinal cracking, which ultimately resulted in overloading failure of the wire rope. To prolong wire rope life, it has been recommended that additional maintenance procedures be introduced such as regular inspection of all machinery in contact with the rope as well as regular lubrication of the wire rope.

 

 


 

 

 

Student Author(s): 

Royce, Liam A.

Department(s):

Wood and Paper Science

Research Mentor(s)

Dimitris Argyropoulos/Wood and Paper Science

Title of Presentation:

Toward Wood-Polyethylene Composites

 

There has been an increasing trend in research to design materials that are both recyclable and biodegradable and able to meet the property requirements. Synthetic-biopolymer blending can add recyclability and biodegradability to a fiber. The possibility of blending modified wood with polyethylene into a fiber was investigated. Southern Pine sawdust was derivatized with palmitoyl chloride in 1-butyl-3-methylimidazolium chloride (BMIMCl). For the first time, a homogeneous reaction became possible. The palmitylated wood was blended with high-density polyethylene in a twin-screw extruder. A take-up system was used to spin the blended material into a homogeneously mixed fiber. This blended material was examined for its thermal properties. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) showed that the product still needed to be purified. This work will continue to have a fundamental understanding of homogeneous derivitization of wood and blending with plastic to produce an advanced wood composite.

 

 


 

 

Student Author(s): 

Seyam, Mohamed A.

Department(s):

Chemical and Biomolecular Engineering

Research Mentor(s)

Richard Spontak/Chemical and Biomolecular Engineering, Materials Science and Engineering

Title of Presentation:

Cross-Linked Polymer Nanocomposites for H2 Gas Separation from CO2

 

 

Gas separation is an important process in the chemical industry, particularly in the separation of the products resulting from the water-gas shift reaction during steam reformation of hydrocarbons. In this process, hydrogen (H2) must be separated from a mixed gas stream containing primarily carbon dioxide (CO2), but also potential trace amounts of water (H2O) and carbon monoxide (CO). Hydrogen gas is utilized in many different ways. For instance, in the growing demand for alternative energy sources, hydrogen fuel cells have emerged as an important consideration. It has become industrially important to reduce energy and economic demands of current gas separation processes and polymer membranes provide an attractive opportunity to achieve this goal. In this study, we have examined the gas separation properties of a cross-linked polyimide containing as-grown palladium (Pd) nanoparticles. Implementation of Pd nanoparticles into these polymer membranes decreases the free volume of the membrane as well as improves the affinity for H2 over other gas species. Additionally, chemical cross-linking of the membranes further reduces free volume and increases chain rigidity, aiding in the prevention of CO2 plasticization and precluding relatively larger gas molecules to penetrate.

 

 


 

 

Student Author(s): 

Sheeran, Paul S. 

Department(s):

Electrical and Computer Engineering

Research Mentor(s)

Maysam Ghovanloo/Electrical and Computer Engineering

Title of Presentation:

DC-DC Converters for Ultra Low-Power Switched-Capacitor Based Implantable Wireless Microstimulating Systems

 

 

Wireless microstimulators are one of the emerging technologies that could be used to treat many biological dysfunctions. Because the battery size takes up a large percentage of the overall space (>50%), reducing its size through efficient power management is crucial in reducing the overall size. This project uses a switched-capacitor stimulation system (SCS) to provide the stimulus through a group of capacitors that are charged regularly by a rechargeable battery using a DC-DC converter. The goal of this research is to identify the favorable characteristics of each potential topology and compare them to determine the best-suited to implement in the SCS system. By finding the most appropriate topology, the overall SCS system will be more effective and more efficient as well as small in its overall size. To approach this I conducted a survey of the literature available on converter topologies and their advantages before looking for the best-suited commercially available samples. I designed the necessary circuits to test each sample and developed a PCB test harness. I had the harness manufactured and constructed the circuits to gather test data of the different chips and how they performed with respect to each other in regard to several parameters. I used this information to determine which DC-DC topology was best suited for the SCS system. My findings show that different topologies yield inherent advantages–some require lower input current while some require less capacitor charge time. Although results have not been finalized yet I expect, based on the preliminary results, that the “synchronous boost converters” will yield advantages in key areas. They seemed to have the best characteristics of input voltage–being able to produce a 5V output at a 0.5V input with the addition of excellent regulation of the signal even as the input voltage exceeded the output voltage.

 

 


 

 

 

Student Author(s): 

Stewart, S. Michael

Department(s):

Chemical and Biomolecular Engineering

Research Mentor(s)

Gregory Parsons/Chemical and Biomolecular Engineering

G. Kevin Hyde/Textiles

Title of Presentation:

Atomic Layer Deposition of Titanium Nitride on Cotton Fabric

 

 

The deposition of titanium nitride onto woven cotton fabric was investigating using an atomic layer deposition method. Untreated cotton samples were dosed using tetrakis(dimethylamino)titanium (TDMAT) and ammonia via an atomic layer deposition (ALD) process in order to attain a controllable, conformal coating on the surface. The aim of these studies was to both verify a practical means of applying a metal thin film to cotton for advanced application, as well as lay the ground work for additional metal deposition, such as silver and copper on cotton, for antimicrobial applications. Deposition was confirmed using x-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES) on cotton and silicon samples, respectively. Physical changes in the cotton after treatment such as color change and hydrophobicity were also investigated. Hydrophobicity was monitored by static water contact angle measurements, and results showed that the surface of the cotton was more hydrophobic than similarly prepared flat surfaces. Work is continuing on this and other metal deposition processes on cotton and other complex surface structures for more permanent antimicrobial application.

 

 


 

 

Student Author(s): 

Stille, John C.

Department(s):

Computer Science

Research Mentor(s)

Tao Xie/Computer Science

Title of Presentation:

Correlating Outputs of Static Code Analysis Tools for Security

 

Static analysis of software code has provided a cost-effective way of managing bugs found throughout the development cycle. Security analysis of software code is a fairly new topic in academia and has been researched through tools, such as LAPSE and FindBugs. The results of different analysis tools on the same code base have been shown to provide different, yet useful, results. When running these tools and having to analyze all of the resulting data, tool users need to overcome a set of encountered problems: in the large amounts of reported data, bugs can seem hidden from developers and bug duplicates must be removed. In our research, we propose a tool that will include modules for parsing output data, to correlate the security vulnerabilities into a standardized XML syntax. Each module will transform data reported by a given analysis tool. The tool will in the end remove duplicates, reduce the number of bugs to help developers prioritize them, and allow multiple tools to provide different results using their heuristics. Through the use of this tool, we expect to provide an easy-to-use API for future static analyzers to plug into our system and exploit the proposed XML schema. Once a standardized output format is created, the time required for data processing will be greatly reduced, saving time, energy, and money for analyzing large projects.

 

 


 

 

Student Author(s): 

Thompson, John F.

Gozen, Arif O.

Department(s):

Chemical and Biomolecular Engineering

Research Mentor(s)

Jan Genzer/Chemical and Biomolecular Engineering Richard J. Spontak/Chemical and Biomolecular Engineering, Materials Science and Engineering

Title of Presentation:

Effect of Added Block Copolymers on Polymer Thin-film Dewetting Rate and Mechanism

 

The stability of thin liquid films of polymers, such as polystyrene (PS) and poly(methyl methacrylate) (PMMA) is important in numerous applications such as printing because adjacent layers of polymers must remain intact and not rupture. Dewetting is a general phenomenon and occurs when a thin liquid film becomes unstable and breaks up as it tries to reduce contact with a surface. Previous studies have shown that PS thin films dewet from PMMA at elevated temperatures. In the system studied here, PS dewets from PMMA and forms holes and then sessile droplets when at temperatures above the upper glass transition temperature. Recent work indicates that the incorporation of a PS-b-PMMA diblock copolymer into the PS can reduce the dewetting rate and change the dewetting mechanism from nucleation and growth to spinodal-like dewetting. The present study addresses the effectiveness of PS-b-PMMA diblock copolymers varying in molecular weight and concentration in PS films varying in thickness, as well as the associated mechanism and rate by which the modified films dewet.

 

 


 

 

Student Author(s): 

Tucker, Jarrod A.

Department(s):

Paper Science Engineering

Research Mentor(s)

Lucian A. Lucia/Paper Science Engineering

Title of Presentation:

Investigation of Acidic Peroxide Pretreatment Upon Hardwood Kraft Pulp Bleaching Costs – A Statistical Designed Investigation of Operating Parameters

 

 

As the profit margin of many grades of paper have narrowed, it has become necessary to optimize and reduce costs throughout the pulpmill, bleach plant, and papermill operations. Chlorine dioxide is the most expensive and most prevalent bleaching chemical used in traditional bleaching sequences and, for this reason there is a need to reduce its usage. Several marginal pretreatment methods have been reported in the literature. Enzyme pretreatment and alkaline peroxide pretreatment have been extensively studied. Enzyme pretreatment has been used to reduce operating costs and increase production, while maintaining current pulp yields and BOD production [1]. One literature source from a British Columbian pulp mill has suggested that improved performance may be obtained by using acidic peroxide. Very little technical work has been done with this pretreatment method. The current study will examine the cost effectiveness, performance, and operational characteristics of acidic peroxide pretreatment of brownstock pulp as a method to reduce the overall bleaching cost. Limited literature data suggests that the use of Fenton Chemistry (acidic peroxide in the presence of ferric iron) as a brownstock pretreatment method will substantially reduce the overall bleaching cost associated with a kraft pulp bleach plant [2]. Initial screening investigations, conducted during the Fall 2006 semester in a mandatory PSE class (WPS 415), suggested that appropriate levels of acidic peroxide application are financially attractive while other levels of acidic peroxide application are cost prohibitive. The use of a statistical designed experimental plan will be employed to examine the response of treatment pH and peroxide charge on total bleaching costs.

 

 


  • Biological Sciences abstracts

Applied Sciences (Crop, Poultry, Animal, and Horticultural Sciences)

Ecology, Environmental, Conservation, Botanical
Molecular, Biochemical, Genetics, Cell Biology
Zoology, Physiology, Behavior, Neurobiology

 


[ 2007 Undergraduate Research Symposium Main Page ]
 

 


Last modified February 2007 by Sharon E. Hunt, WordHunting