The 7th
Annual
NC
Undergraduate
Summer Research Symposium
Sustainability,
Engineering and the Environment (SEE) abstracts
Abstracts are listed in
alphabetical order by the last name of the corresponding author.
|
Blodgett, Steven M. |
|
|
Home Institution: |
Arizona State University |
|
Program: |
Sustainability, Engineering and the Environment
(SEE) |
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College: |
Natural Resources |
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Department(s): |
Wood and Paper Science |
|
Research |
Joel J. Pawlak/Wood and Paper Science |
|
Title of Presentation: |
Chemically Untreated
Micro-Fibrillated Cellulose as a Replacement for Petrochemical Derived
Plastic Films |
Cellulose, the main
ingredient of plant cell walls, is the most abundant natural resource on the
planet. It is a renewable, non-toxic, bio-degradable material. The main
objective of this experiment was to determine whether chemically untreated
cellulose can be used as a replacement for petrochemical derived plastic films.
Micro-Fibrillated Cellulose was produced by extensive mechanical beating of
commercial bleached softwood Kraft pulp. This highly fibrillated pulp was
diluted to form a cellulose and water suspension of about 0.2%
consistency. The cellulose was then formed into a film by a vacuum
forming method. The films were dried under varying temperature and pressure
in a heat press. The resulting films were characterized for their
mechanical properties, water absorbent properties, and barrier
properties.
|
Brown, Kwame J. |
|
|
Home Institution: |
North
Carolina A&T State University |
|
Program: |
Sustainability,
Engineering and the Environment (SEE) |
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College: |
Engineering and Technology |
|
Department(s): |
Chemical and Biomolecular
Engineering |
|
Research Mentor(s): |
George
Roberts/Chemical and Biomolecular Engineering |
|
Title of Presentation: |
Recovering
a Purer Hydrogenated Polystyrene |
A methodological approach for the extraction of partially hydrogenated
polystyrene (PS) was studied. Hydrogenation improves polymer properties such as
thermal resistance. It has been reported that fully hydrogenated PS has a glass
transition temperature, Tg, which is approximately 40 degrees higher
than PS (105°C).
In this work we are examining the Tg of partially hydrogenated PS using
differential scanning calorimetry (DSC). The dilemma is that the Tg
of our partially hydrogenated PS was less than what was expected. We believe
DSC data shows there is possible solvent contamination in the polymer samples,
which can distort Tg readings. A multi-step extraction method of
polymer recovery was studied to try to obtain a more pure polymer product. The
multi-step extraction method first involved separating the dissolved polymers
in decahydronaphthalene from the catalyst. The polymers were then precipitated
in methanol, dried, dissolved in toluene, and re-precipitated in methanol. This
method produced powder forms of partially hydrogenated PS after the second
extraction. The powder form allows for better solvent removal during drying.
Preliminary results of polymers created at similar reaction conditions and
recovered using multi-step extraction showed an increase in Tg
readings and a decrease in percent weight loss of the samples. This indicates
the multi-step method is removing the impurities that affect Tg. The
effects of the reaction conditions, variation of catalyst ratio with and
without CO2 and variation of reaction times at 120°C and 180°C, on Tg data is
also being studied.
|
Exton, Andrew C. Arvidson, Sara A. |
|
|
Home Institution: |
University of Toledo |
|
Program: |
Sustainability, Engineering and the Environment
(SEE) |
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College: |
Engineering and Technology |
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Department(s): |
Chemical and Biomolecular
Engineering |
|
Research |
Saad A. Khan/Chemical and Biomolecular Engineering |
|
Title of Presentation: |
Molecular Weight Effects
on Gelation and Rheological Characteristics of Guar Galactomannan |
Guar galactomannan, a
naturally occurring polysaccharide, has a wide array of uses, ranging from drug
delivery, food additives to enhanced oil and gas production. In particular,
because of its low cost, natural abundance and ability to impart high viscosity
in aqueous solution at low concentration, it is an ideal substance for use as
an environmentally benign hydraulic-fracturing fluid. In this project, we
examine ways to modulate the rheology of guar using (a) guar of different
molecular weights either individually or as blends and (b) crosslinking with
borax. While high molecular weight (1.6 million Da) HMW native guar transforms
from a high viscosity liquid to a gel upon addition of borax, no such sol-gel
transition is observed with the hydrolyzed low molecular weight LMW guar, even at
much higher concentrations. As for blend behavior, even small additions of LMW
guar to HMW guar significantly alter the gelation behavior and rheological
characteristics of the sample. These results taken together indicate that blend
composition and degree of crosslinking can be exploited to tailor the rheology
of hydraulic fracturing fluids.
|
Green, Kyle H. |
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Home Institution: |
North Carolina A&T
State University |
|
Program: |
Sustainability,
Engineering and the Environment (SEE) |
|
College: |
Engineering and Technology |
|
Department(s): |
Chemical and Biomolecular
Engineering |
|
Research Mentor(s): |
Steven Peretti/Chemical
Engineering |
|
Title of Presentation: |
An Effective Method of
Measurement of Lipase Activity |
With the cost of motor fuel
rising across the nation, biodiesel production is being looked at more as an
alternative fuel solution. According to the National Biodiesel Board’s website,
biodiesel production in the US has increased from 2 million gallons in the year
2000, to 450 million gallons in the year 2007. Currently, biodiesel is produced
from virgin soybean oil. While effective and efficient processes have been
developed around these feed stocks, vegetable oils are growing more expensive.
As an alternative, the use of lower quality oils has been tested, but they
contain higher water and free-fatty acid contents. The elevated water and
free-fatty acid content disrupt the standard reaction chemistry, and require
additional processing steps. The use of lipases as a catalyst is the most
effective way of producing biodiesel using low quality feed stocks, because
they are effective in converting free-fatty acids into biodiesel and relatively
unaffected by the presence of water. Using lipases as a catalyst, however, is
also very expensive, due primarily to the price of lipase purification. The
goal of this project is to develop a more economically effective method of
producing biodiesel from vegetable oil by studying lipases expressed by the
fungus Rhizopus oryzae and Aspergillus oryzae. We intend to use lipases
expressed by the immobilized fungus to eliminate the cost of lipase
purification. In order to measure the lipase activity expressed by these two
fungi, a hydrolytic activity assay was developed to detect enzymatic activity
both inside and outside the cell. The assays were performed on fungus
grown under several different conditions, to determine enzyme stability,
reaction rates, and the specific activity of the fungal cultures. With an
effective method of characterizing lipase activity, a process can be designed
that produces biodiesel without using purified lipases.
|
Grubaugh, Phillip |
|
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Home Institution: |
Elon University |
|
Program: |
Sustainability,
Engineering and the Environment (SEE) |
|
College: |
Engineering and Technology |
|
Department(s): |
Chemical and Biomolecular
Engineering |
|
Research Mentor(s): |
Steven W. Peretti/Chemical
and Biomolecular Engineering |
|
Title of Presentation: |
Mathematical Models of
Select Biocatalysts for Metabolic Engineering Efforts to Generate Ethanol
from Synthesis Gas |
In the US, ethanol production
nearly doubled between 2000 and 2006, when 4.86 billion gallons were produced.
This used roughly 18 percent of the nation’s corn harvest in 2006, and according to the USDA, by
2009 there are estimates to use 30 to 35 percent of the harvest. A single
bushel of corn weighs in at 56 lbs. and can only produce 2.8 gallons of ethanol
through traditional fermentation processes. To many, this would seem like a
waste of a quality food item, and at current corn prices, ethanol production
operates close to break even economically. In light of this, more sustainable
and viable options have been sought out. Using non-food feedstocks, like
grasses and woody biomass, is proposed as an alternative to corn starch. Since
fermentation of these materials is not efficient, thermal decomposition of this
biomass, called gasification, is the preferred processing route. This route
produces “syngas”, a combination of hydrogen, carbon monoxide and
carbon dioxide. Recently, a path has been discovered to convert syngas, using biocatalysts
such as Clostridium acetobutylicum and Methylobacterium extorquens strains, to
end products that include ethanol. Effective operation of this process requires
mathematical modeling of cellular metabolism for each organism. Modeling each
step of the conversion using MATLAB software, the differential equations
effectively describe the process. This model is continually modified to find
what the limiting substrates are and find what effectively are the essential
building blocks for the ethanol end product.
|
Hartley, Douglas Bonino, Christopher |
|
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Home Institution: |
Georgia Institute of
Technology |
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Program: |
Sustainability,
Engineering and the Environment (SEE) |
|
College: |
Engineering and Technology |
|
Department(s): |
Chemical and Biomolecular
Engineering |
|
Research Mentor(s): |
Saad Khan/Chemical and
Biomolecular Engineering |
|
Title of Presentation: |
Electrospun Nanofibers for
Lithium Ion Battery Applications |
The superior energy density
and environmentally benign nature of rechargeable lithium ion batteries make
them highly desirable in many applications, from consumer electronics to
satellites. In this project we combine the desirable attributes of this
technology with nanomanufacturing to develop novel materials as components for
new generation batteries. In particular, we developed nanoparticle-containing
nanofibers, using the electrospinning process. Composite nanofibers of
polyacrylonitrile (PAN) were prepared with tin dioxide, titanium dioxide, and
silicon dioxide nanoparticles. PAN nanofibers were also carbonized in a
furnace with a controlled atmosphere to form carbon nanofibers. The
polymer solution concentration, conductivity, and viscosity were varied to
study the effects on morphology and nanoparticle distribution of the
electrospun fibers. Additionally, the relationship between the
carbonization conditions and the final fiber diameter was investigated.
|
Hicks, Tyrik T. |
|
|
Home Institution: |
NCSU |
|
Program: |
Sustainability,
Engineering and the Environment (SEE) |
|
College: |
Engineering and Technology |
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Department(s): |
Chemical and Biomolecular
Engineering |
|
Research Mentor(s): |
George
W. Roberts/Chemical and Biomolecular Engineering |
|
Title of Presentation: |
Measurement
and Modeling of the Viscosity of Polystyrene in Supercritical CO2 Expanded
Decahydronaphthalene |
Viscosity measurements have
been taken on an oscillating piston high pressure viscometer.
Measurements have been conducted on 420,000 g/mol polystyrene with a
polydispersity index of 1.15 in a solvent mixture consisting of 76/24 wt% trans/cis-decahydronaphthalene
(DHN). The polymer concentration range investigated was 0.25 to 11.0
wt%. At each polymer concentration the temperature was varied from
approximately 35 to 150oC. All polystyrene/DHN solution
viscosities were measured at the vapor pressure of the solution. The
viscosity ranged from 200 cP at 35oC and 11 wt% PS to 0.55 cP at 147
oC and 0.25 wt% polystyrene. Each concentration showed a
decrease in viscosity with an increase in temperature. A free volume
model concept has been applied to all of the viscosity data and has proven to
capture the behavior of the data fairly well. The model requires three
pure component parameters and appropriate mixing rules have been applied for
mixture viscosity modeling. Preliminary data was taken on the same
solutions, but with the addition of supercritical carbon dioxide (scCO2).
The addition of scCO2decreases the solution viscosity, in most cases
by an order of magnitude with the addition of approximately 18 wt% CO2.
Phase equilibria studies show that CO2 is an antisolvent for
polystyrene, thus there is a limit to the amount of CO2 that can be
added to the system before precipitation occurs. The current viscosity
data on polystyrene/DHN/CO2 solutions was obtained at 3000
psig. At low pressures, CO2 partitions between the dense
polystyrene/DHN rich phase and the light CO2 rich phase. High
pressure is required to force the CO2 rich phase into the liquid
phase for one fluid phase viscosity measurements to be taken over the whole
range of temperatures.
|
Houghton, Elizabeth |
|
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Home Institution: |
NCSSM |
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Program: |
Sustainability, Engineering
and the Environment (SEE) |
|
College: |
CALS |
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Department(s): |
Biological and
Agricultural Engineering |
|
Research |
Ratna
Sharma-Shivappa/Biological and Agricultural Engineering Steve Peretti/Chemical
Engineering |
|
Title of Presentation: |
Pretreatment of Miscanthus
for Conversion to Cellulosic Ethanol |
Pretreatment is one of the most important and expensive steps in the process of
making cellulosic ethanol. It must reduce cellulose crystallinity while minimizing
degradation of sugars and remaining cost-effective. Because of the varying
properties of the feedstocks that can be converted into cellulosic ethanol,
pretreatments vary in performance efficiency. Miscanthus, a tall perennial
grass, holds exciting potential as an energy crop and is currently being
investigated for its compositional properties, their relationship to
pretreatment effectiveness, and how it responds to differences in pretreatment
conditions. Composition analyses of miscanthus at 8.48% moisture dry basis are
being conducted to determine the ash, acid soluble and insoluble lignin, and
sugar content of the raw biomass. Pretreatments using sulfuric acid or sodium
hydroxide are being conducted in the autoclave at 121°C and 15 psi for 60 minutes. Pretreated biomass
subjected to enzymatic hydrolysis will help to determine the pretreatment
efficiency by allowing a comparision of the release of fermentable sugars from
pretreated and untreated biomass.
|
Huang, Baozhen |
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Home Institution: |
NCSU |
|
Program: |
Sustainability,
Engineering and the Environment (SEE) |
|
College: |
Engineering and Technology |
|
Department(s): |
Chemistry
and Biological Science |
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Research Mentor(s): |
William L. Roberts/Mechanical
and Aerospace Engineering Larry F.
Stikeleather/Biological and Agricultural Engineering |
|
Title of Presentation: |
Jet
Fuel from Vegetable Oil via Decarboxylation |
The objective for this research
is to explore the feasibility for production of aviation biofuel from vegetable
oil by using CentiaTM technology. The term CentiaTM is derived
from the Latin term “green power”. CentiaTM
provides solution for high efficiency, affordability, and feedstock flexibility
in aviation biofuel production process developed by North Carolina State
University (NCSU). DEC (Diversified Energy Corporation) will be sole authorized
marketer for CentiaTM technology. The process of CentiaTM
consists of three different steps; high temperature and pressure hydrolysis of
lipid feedstock into free fatty acids and glycerol, catalytic decarboxylation
of free fatty acids into straight n-alkane chains (15-17 C), and the changing
of chemical and physical properties of n-alkane chains by hydroisomerization
/hydrostacking of straight alkane chains into mixture of shorter n-alkane
chains, isoalkanes, cycloalkanes, and aromatics. The by-product glycerol
obtained from the process can be burned off to provide heat in various parts of
the process. The goal for this project is to commercialize the
technology to produce affordable aviation biofuel while maximizing overall
energy efficiency approaching 90%. The future studies for this project are to
find an alternative way for hydrolysis and enhance the technology by increasing
the energy eifficiency.
|
Kalanyan, Berc Glicksman, Matthew |
|
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Home Institution: |
Lehigh University |
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Program: |
Sustainability,
Engineering and the Environment (SEE) |
|
College: |
Engineering and Technology |
|
Department(s): |
Chemical and Biomolecular
Engineering |
|
Research Mentor(s): |
Gregory Parsons/Chemical
and Biomolecular Engineering |
|
Title of Presentation: |
Fabrication of a Dye-Sensitized
Electrochemical Photovoltaic Cell |
The manufacturing of
commercial monocrystalline silicon photovoltaic cells is both hazardous and
expensive. A new generation of solar cells can avoid semiconductor fabrication and
provide an easy-to-assemble cell made from inexpensive materials. The objective
of this study was to manufacture a Grätzel-type dye-sensitized electrochemical
photovoltaic cell that would produce a positive voltage and current. The cell
was fabricated from a translucent electrode (FTO glass) on the front, a TiO2
layer sensitized with the dye Ru 535-bisTBA, an electrolyte solution of KI/I in
ethylene glycol, and a counter electrode made of Pt- or Au-coated ITO glass.
The IV response and the power output of the cell were tested using a source
meter. Experiments performed included the preparation of a TiO2
paste in varying compositions, the comparison of lab-made TiO2 paste
to a commercial TiO2 nanoparticle solution, the use of two different
counter electrodes (Au and Pt), various masking methods for sealing the cells,
and the variation of sealant thickness. The results indicate that there was no
discernible difference between commercial and in-house TiO2 pastes.
Several steps in cell manufacturing were improved, including template and TiO2
paste preparation. It was also determined that a cell sealed with
thermally-activated sealant is susceptible to clogging when electrolyte is
injected into the cell, whereas a pressure-sealed cell is easily filled with
electrolyte. The cells manufactured in the lab produced a current density of
about 3µA/cm and a photovoltage of 50mV. The very low current densities and
photovoltages suggest that further study in cell fabrication is necessary. The
effects of Au and Pt electrodes, as well as the effects of sealant thickness
will be investigated.
|
Liloudini, Arouna |
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Home Institution: |
NCSU |
|
Program: |
Sustainability,
Engineering and the Environment (SEE) |
|
College: |
Engineering and Technology |
|
Department(s): |
Chemical and Biomolecular
Engineering |
|
Research Mentor(s): |
Tamer
S. Ahmed/Chemical and Biomolecular Engineering Yazan
A. Hussain/Chemical and Biomolecular Engineering |
|
Title of Presentation: |
Behavior
of the Quartz Crystal Microbalance (QCM) under High Pressure of Carbon
Dioxide |
Quartz Crystal Microbalance
(QCM) is a useful technique to study the sorption into polymers especially at high
pressures. The variation of the frequency of a quartz crystal helps in
evaluating the effect of temperature, pressure, coating thickness, or polymer
molecular weight on the kinetics of the sorption process. The main objective of
the current research is to study the sorption of carbon dioxide into
poly(methyl methacrylate) using QCM. The effects of temperature (25-55 oC),
pressure (up to 3500 psi), and polymer molecular weight (15,000–966,000 g/mol)
have been evaluated. This research helps in having more fundamental
understanding about the sorption of carbon dioxide in polymers.
|
Mullen, Keena A. E. |
|
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Home Institution: |
Washington State
University |
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Program: |
Sustainability, Engineering and the Environment
(SEE) |
|
College: |
Engineering and Technology |
|
Department(s): |
Chemical and Biomolecular
Engineering |
|
Research |
Wesley A. Henderson/Chemical and Biomolecular
Engineering |
|
Title of Presentation: |
Ionic Liquids as Solvents for
Lignocellulosic Biomass |
The production of biofuels has risen in recent years
in response to the increasing cost of petroleum products. Of all natural
sources of energy for biofuel production, lignocellulosic biomass is the most
prevalent and least expensive. Lignocellulosic biomass is comprised of lignin
and the polysaccharides hemicellulose and cellulose. To obtain energy for
biofuels, the polysaccharides must be hydrolyzed into their constituent sugars.
This is difficult for three reasons: the lignin closely binds the
polysaccharides together, the cellulose is often highly crystalline (resulting
in less reactive sites for dissolution), and the lignin and cellulose are
essentially insoluble in common solvents. Solvents known as ionic liquids have
been shown to dissolve both cellulose and lignin in high concentrations. Ionic
liquids are salts with low melting temperatures (less than 100º C) that can be
recycled after use as biopolymer solvents. This project explores how the
structural features of the component ions of the ionic liquids influences
biopolymer solubility.
|
Park, Andrew M. |
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Home Institution: |
Clemson University |
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Program: |
Sustainability, Engineering and the Environment
(SEE) |
|
College: |
Engineering and Technology |
|
Department(s): |
Wood and Paper Science |
|
Research |
Martin Hubbe/Wood and Paper Science John Heitmann/Wood and Paper Science |
|
Title of Presentation: |
Green Technologies to Promote
Water Release during Paper Manufacture |
When making paper, one of the most energy intensive
steps is the dewatering process. Large rotating dryer cans are needed to
facilitate the evaporative drying of wet paper sheets. One can save much energy
if the dewatering process is made faster so that less water remains in the web
once it gets to the dryer cans. It has been proposed that fine particles,
or fines, are the variable contained in paper pulp that affects dewatering most
significantly. The first purpose of this study was to classify fine
particles into different groups based on size. A Bauer-McNett apparatus was
used to differentiate the fines, using 48, 100, 150, and 200 mesh screens. Four
classes of fines – R100, R150, R200, and P200 – were created. With the fines
separated by size, they could then be added in different combinations to
recycled paper fibers in order to perform freeness tests with a modified
Schopper-Riegler device. Tests were conducted with both one class of fines
added at 30% solids concentration and two classes each added together at 15%
concentration. The fines that hindered dewatering the most were found by
comparison. In the future, pre-treatment with polyelectrolytes or enzymes can
target these fines before the evaporative drying phase in papermaking so that
dewatering can proceed faster, using less energy.
|
Scrivner, Katie |
|
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Home Institution: |
University of Puget Sound |
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Program: |
Sustainability, Engineering and the Environment
(SEE) |
|
College: |
CALS |
|
Department(s): |
Biological and
Agricultural Engineering |
|
Research |
Mari Chinn/Biological and Agricultural Engineering |
|
Title of Presentation: |
Simultaneous
Saccharification and Fermentation of FTA 94 Sweetpotatoes |
Industrial sweetpotatoes offer an alternative starch
resource to corn for the production of fuel ethanol and high value chemicals
that can contribute to the diversification of renewable plant-based feedstocks
and participation of the southeast region in enhancing energy security. The
starch to ethanol conversion process involves 1) liquefaction at -amylase
enzymes to swell starch granules and breakdowna85°C with
amylose and amylopectin polymers to short dextrin sugars; 2)
saccharification with glucoamylase enzymes to convert dextrins to fermentable
glucose; and 3) yeast fermentation of glucose under anaerobic conditions to
ethanol. The simultaneous processing of enzymatic conversion and
fermentation can reduce the number of processing steps and improve energy
efficiency, therefore making it more environmentally and economically
practical. The objective of this project was to asses the feasibility of
simultaneous saccharification and fermentation (SSF) for the conversion of
industrial FTA-94 sweetpotatoes to ethanol and investigate processing
parameters significant to the combined process. Factors evaluated
included glucoamylase loading rates (no enzyme, 2.5 AGU/g dry sweetpotato, and
5 AGU/g dry sweetpotato), yeast concentration (no yeast, 0.1% w/v and 1% w/v)
and incubation time (0 to 72 hours). The overall ethanol yield and
residual sugars produced over time in SSF were measured and differences between
treatment combinations were compared. Put results here when we have
them.
|
Winkler, James D. |
|
|
Home Institution: |
Rice University |
|
Program: |
Sustainability, Engineering and the Environment
(SEE) |
|
College: |
Engineering and Technology |
|
Department(s): |
Biological and
Agricultural Engineering |
|
Research |
Ratna Sharma/Biological and Agricultural
Engineering Mari Chinn/Biological and Agricultural Engineering |
|
Title of Presentation: |
Production of Poly
(3-Hydroxybutyric Acid) from Waste Sweet Potato Starch |
The organism Ralstonia eutropha has been shown to
produce Poly (3-Hydroxybutyric Acid) (PHB), a biodegradable polymer similar to polypropylene,
efficiently under a variety of nutrient limiting conditions. The utilization of
excess agricultural starch as the carbon source to support R. eutropha allows
for the creation of a valuable product from a waste product stream. This
project explored the production of PHB by R. eutropha within 150 mL stationary
batch reactors, utilizing glucose or processed industrial sweet potato flour
(ISP-94) as carbon substrates. The optical density of R. eutropha culture
solution was tracked to develop a logistic growth equation identifying the lag,
log, and stationary phases of bacterial growth. Fluorescent microscopy was used
to detect the presence of PHB inclusions within colonies incubated in the
nitrogen limited media prior to chloroform-hypochlorite extraction of PHB.
Final yields of biomass and PHB were measured to quantify process efficiency.
These results indicate that hydrolyzed ISP-94 starch may serve as a carbon
source for R. eutropha PHB production within laboratory scale batch reactors.
|
Wood, Sean M. |
|
|
Home Institution: |
Georgia Institute of
Technology |
|
Program: |
Sustainability, Engineering and the Environment
(SEE) |
|
College: |
Engineering and Technology |
|
Department(s): |
Biological and Agricultural
Engineering |
|
Research |
Mari S. Chinn/Biological and Agricultural Sciences G. Craig Yencho/Horticultural Science |
|
Title of Presentation: |
Production and Scaled-up
Biocatalytic Conversion of Industrial Sweetpotatoes to Useful Sugars |
Currently, fuel ethanol is heralded as the ideal
solution to the energy crisis facing the United States. However, the majority
of fuel ethanol is produced from corn, which 1) is limited in supply; 2) has a negative
impact on feed markets; and 3) only truly benefits the Midwest region as a
gasoline alternative. Feedstock diversification will be necessary to improve
energy security and sustainability. Industrial sweetpotatoes have a high dry
matter content (>30%), so they offer an alternative starch resource that
does not compete with food or feed markets and can be converted to fermentable
sugars. North Carolina, which produced 43% of the nation’s sweetpotatoes in
2006, is well-suited to support the development of this starch-based feedstock
for use in production of renewable fuels and chemicals. Enzymatic processing
parameters necessary to convert industrial sweetpotato FTA-94 starch to glucose
have been investigated at a small lab scale (~3 grams dry matter). This project
focuses on scaling up the hydrolysis steps (liquefaction and saccharification)
of the overall sweetpotato to ethanol conversion process, which will
demonstrate the feasibility of using sweetpotatoes at a pilot and commercial
scale. The objective of this work was to observe the effects that scale (3g
-> 15.6g -> 31.25g -> 62.5g -> 150g) and agitation have on overall
conversion efficiency of fresh and flour sweetpotato preparations. It is
hypothesized that: 1) the dry preparation will be more efficient since the
smaller particle size increases surface area for enzyme attachment; 2)
agitation will keep the enzyme dispersed uniformly, thus significantly
improving the breakdown of starch into glucose; and 3) the overall process will
scale up relatively uniformly with little change in conversion efficiencies.
Results from this project will indicate which aspects of liquefaction and
saccharification need to be altered to increase conversion efficiencies.
|
Ziaja, Sarah E. |
|
|
Home Institution: |
University of Portland |
|
Program: |
Sustainability, Engineering and the Environment
(SEE) |
|
College: |
Natural Resources |
|
Department(s): |
Forestry |
|
Research |
Chris Hopkins/Forestry Preston Burnette/Poultry Science |
|
Title of Presentation: |
Construction and Analysis
of Mobile Torrefaction Processor |
There is an increasing need to efficiently and
effectively process biomass in order to use it as a fuel source. Torrefaction
is a technology that can meet this demand. During the torrefaction process
plant material is converted from a moist, fibrous, perishable waste material
into a dry, easily ground, stable fuel that can be sold as a coal substitute.
In the low energy input process of torrefaction, hemicellulose - which is a
polymer of biomass - is pyrolized while the moisture and volatile organics are
removed from the biomass creating a much more energy dense fuel. The gases and
liquids produced during the process can be combusted and circulated as an
energy integration method. Torrefied wood chips have an energy density over two
times that of raw wood chips per unit weight. This energy densification
increases the profitability of wood being transported for the purpose of energy
consumption. This project involves the construction of a mobile torrefaction
processor, which involves cutting, welding, and bolting of steel plates and
parts together along with the installation of motors and gears that run the
machine. Continuing work entails the installation of probes and the burner
section of the processor.
[ Participant Listing
| Abstracts ]
Last modified June 2008 by Sharon E. Hunt